Functionalized expanded porphyrins

Sessler, Jonathan L; Pantos, Patricia J

Title: Functionalized expanded porphyrins

Patent · Tue Nov 12 00:00:00 EST 2013

OSTI ID:1107917

Sessler, Jonathan L; Pantos, Patricia J

Disclosed are functionalized expanded porphyrins that can be used as spectrometric sensors for high-valent actinide cations. The disclosed functionalized expanded porphyrins have the advantage over unfunctionalized systems in that they can be immobilized via covalent attachment to a solid support comprising an inorganic or organic polymer or other common substrates. Substrates comprising the disclosed functionalized expanded porphyrins are also disclosed. Further, disclosed are methods of making the disclosed compounds (immobilized and free), methods of using them as sensors to detect high valent actinides, devices that comprise the disclosed compounds, and kits.

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Research Organization:: The University of Texas (Austin, TX)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG03-01ER15186

Assignee:: Board of Regents, The University of Texas System (Austin, TX)

Patent Number(s):: 8,580,845

Application Number:: 12/664,524

OSTI ID:: 1107917

Country of Publication:: United States

Language:: English

References (53)

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