skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Self assembled multi-layer nanocomposite of graphene and metal oxide materials

Patent ·
OSTI ID:1107606

Nanocomposite materials having at least two layers, each layer consisting of one metal oxide bonded to at least one graphene layer were developed. The nanocomposite materials will typically have many alternating layers of metal oxides and graphene layers, bonded in a sandwich type construction and will be incorporated into an electrochemical or energy storage device.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC0676RLO1830
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Number(s):
8,563,169
Application Number:
13/585,741
OSTI ID:
1107606
Country of Publication:
United States
Language:
English

References (138)

Templating of Mesoporous Molecular Sieves by Nonionic Polyethylene Oxide Surfactants journal September 1995
Carbon materials metal/metal oxide nanoparticle composite and battery anode composed of the same patent August 2006
Process for the preparation of metal-containing nanostructured films patent February 2006
Improved electrochemical performance of a LiFePO4-based composite cathode journal August 2001
Self-Healing of Surfactant Surface Micelles on Millisecond Time Scales journal September 2006
Supramolecular Self-Assembly of Lipid Derivatives on Carbon Nanotubes journal May 2003
Layer-By-Layer Assemblies of Carbon-Based Nanostructures and Their Applications in Energy Storage and Generation Devices patent-application June 2010
Sonochemical Synthesis of Nanostructured Molybdenum Sulfide journal June 1998
Structural, electronic and magnetic properties of manganese doping in the upper layer of bilayer graphene journal April 2008
Electrochemical Lithium Intercalation into a Polyaniline/V[sub 2]O[sub 5] Nanocomposite journal January 1996
Improved Electrode Performance of Porous LiFePO4 Using RuO2 as an Oxidic Nanoscale Interconnect journal August 2007
Conductive nanocomposite-based electrodes for lithium batteries patent-application December 2009
Periodic mesoporous organosilicas with organic groups inside the channel walls journal December 1999
Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets journal November 2007
Issues and challenges facing rechargeable lithium batteries journal November 2001
Mesoporous Metal Oxide Graphene Nanocomposite Materials patent-application March 2011
Graphene-based structure, method of suspending graphene membrane, and method of depositing material onto graphene membrane patent-application November 2009
Low-Temperature Synthesis of Tunable Mesoporous Crystalline Transition Metal Oxides and Applications as Au Catalyst Supports journal August 2008
Metal Oxide/Hydroxide Materials patent-application December 2007
Room temperature synthesis and Li insertion into nanocrystalline rutile TiO2 journal August 2006
Formation of Positronium in Cup-Stacked Carbon Nanofibers journal January 2004
Mesoporous network electrode for electrochemical cell patent-application July 2004
In situ chemical synthesis of SnO2–graphene nanocomposite as anode materials for lithium-ion batteries journal October 2009
Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites journal August 1997
Method of producing exfoliated graphite, flexible graphite, and nano-scaled graphene platelets patent-application November 2008
Method for producing nanocarbon materials patent-application May 2003
Thermal Conductivity of Pure and Impure Silicon, Silicon Carbide, and Diamond journal December 1964
Nanocomposite of graphene and metal oxide materials patent September 2012
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores journal January 1998
Pseudocapacitive Lithium Storage in TiO2(B) journal March 2005
Lithium Ion Batteries with Titania/Graphene Anodes patent-application May 2011
Nanocrystalline ceramic materials reinforced with single-wall carbon nanotubes patent-application August 2004
Lithium Insertion into TiO[sub 2] Nanotube Prepared by the Hydrothermal Process journal January 2003
H–T phase diagram and the nature of vortex-glass phase in a quasi-two-dimensional superconductor: Sn-metal layer sandwiched between graphene sheets journal February 2004
Nanocomposite of Graphene and Metal Oxide Materials patent-application November 2012
Characteristics of graphene-layer encapsulated nanoparticles fabricated using laser ablation method journal April 2008
SnO2-carbon composites for lithium-ion battery anodes journal June 2001
TiO2(B) Nanowires as an Improved Anode Material for Lithium-Ion Batteries Containing LiFePO4 or LiNi0.5Mn1.5O4 Cathodes and a Polymer Electrolyte journal October 2006
Preparation and characterization of graphene oxide paper journal July 2007
Self-assembly of nanocomposite materials patent July 2001
Water-based gravure printing ink patent October 1999
Dispersion of Sn and SnO on carbon anodes journal September 2000
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism journal October 1992
Thermally exfoliated graphite oxide patent-application April 2007
Functionalized Single Graphene Sheets Derived from Splitting Graphite Oxide journal May 2006
Self-Assembled TiO 2 –Graphene Hybrid Nanostructures for Enhanced Li-Ion Insertion journal March 2009
Functionalized graphene sheets for polymer nanocomposites journal May 2008
Enhanced Cyclic Performance and Lithium Storage Capacity of SnO 2 /Graphene Nanoporous Electrodes with Three-Dimensionally Delaminated Flexible Structure journal January 2009
Wire Coating Containing Thermally exfoliated Graphite Oxide patent-application December 2008
Structural changes of a pyrolytic graphite surface oxidized by electrochemical and plasma treatment journal June 1994
High Performance Batteries with Carbon Nanomaterials and Ionic Liquids patent-application October 2009
RuO2-wired high-rate nanoparticulate TiO2 (anatase): Suppression of particle growth using silica journal June 2008
Assembly and Properties of Nanoparticles book January 2009
Graphite platelet nanostructures patent-application May 2002
Nanocrystalline Rutile TiO[sub 2] Electrode for High-Capacity and High-Rate Lithium Storage journal January 2007
Purification and size-selection of carbon nanotubes journal January 1997
Nanocrystalline TiO[sub 2] (Anatase) Electrodes: Surface Morphology, Adsorption, and Electrochemical Properties journal January 1996
Nanostructured materials for advanced energy conversion and storage devices journal May 2005
High Lithium Electroactivity of Nanometer-Sized Rutile TiO2 journal June 2006
Flexible Graphene Films via the Filtration of Water-Soluble Noncovalent Functionalized Graphene Sheets journal May 2008
Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries journal August 2008
Synthesis of Water Soluble Graphene journal June 2008
TiO 2 -Graphene Nanocomposites. UV-Assisted Photocatalytic Reduction of Graphene Oxide journal July 2008
Van Der Waal’s Elastica conference January 2005
Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite journal September 2007
Carbon fine powder coated with metal oxide, metal nitride or metal carbide, process for producing the sdame, and supercapacitor and secondary battery carbon fine powder patent-application July 2006
Citrate-Derived Carbon Nanocoatings for Poorly Conducting Cathode journal January 2006
Thin-film-like particles having skeleton constructed by carbons and isolated films patent-application February 2002
A Mesoporous Nanocomposite of TiO2 and Carbon Nanotubes as a High-Rate Li-Intercalation Electrode Material journal January 2006
Hierarchical battery electrodes based on inverted opal structures journal August 2002
Mesoporous tin oxides as lithium intercalation anode materials journal January 2002
Sorting of single-walled carbon nanotubes using optical dipole traps patent-application June 2004
Synthesis and Li-Ion Insertion Properties of Highly Crystalline Mesoporous Rutile TiO 2 journal May 2008
Impact of the Carbon Coating Thickness on the Electrochemical Performance of LiFePO[sub 4]/C Composites journal January 2005
Superior Electrode Performance of Nanostructured Mesoporous TiO2 (Anatase) through Efficient Hierarchical Mixed Conducting Networks journal August 2007
TiO2-B Nanowires journal April 2004
Molecular Dynamics Simulations of Surfactant Self-Organization at a Solid−Liquid Interface journal January 2006
Oriented Nanostructures for Energy Conversion and Storage journal September 2008
Layer-Layer Lithium Rich Complex Metal Oxides with High Specific Capacity and Excellent Cycling patent-application March 2011
Fullerene Nanotube Compositions patent-application March 2008
Nanoionics: ion transport and electrochemical storage in confined systems journal November 2005
Magnetically directed self-assembly of submicron spheres with a Fe3O4 nanoparticle shell journal February 2002
Conductive ink containing thermally exfoliated graphite oxide and method of making a conductive circuit using the same patent-application December 2008
Organization of Organic Molecules with Inorganic Molecular Species into Nanocomposite Biphase Arrays journal August 1994
Nanoporous Electrodes and Related Devices and Methods patent-application December 2009
Nano-scaled graphene plate nanocomposites for supercapacitor electrodes patent November 2009
Electronic Confinement and Coherence in Patterned Epitaxial Graphene journal May 2006
Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries patent-application December 2009
Reducing Carbon in LiFePO[sub 4]/C Composite Electrodes to Maximize Specific Energy, Volumetric Energy, and Tap Density journal January 2002
Molecular self-assembly and nanochemistry: a chemical strategy for the synthesis of nanostructures journal November 1991
Block copolymer processing for mesostructured inorganic oxide materials patent February 2007
Microemulsion Syntheses of Sn and SnO[sub 2]-Graphite Nanocomposite Anodes for Li-Ion Batteries journal January 2004
Sonochemical synthesis of amorphous iron journal October 1991
Nano-network electronic conduction in iron and nickel olivine phosphates journal February 2004
Semiconducting superlattices templated by molecular assemblies journal March 1996
Graphite Oxide-Intercalated Anionic Clay and Its Decomposition to Graphene−Inorganic Material Nanocomposites journal August 2008
Nano graphene platelet-based composite anode compositions for lithium ion batteries patent-application May 2009
Highly conductive nano-scaled graphene plate nanocomposites and products patent-application July 2007
Titania-Graphene Anode Electrode Paper patent-application April 2012
Atomic Layer Deposition of Metal Oxides on Pristine and Functionalized Graphene journal July 2008
Mesoporous composite gels an aerogels patent December 2002
Self assembled multi-layer nanocomposite of graphene and metal oxide materials patent-application February 2011
Mesoporous Platinum Films from Lyotropic Liquid Crystalline Phases journal October 1997
Assembly of chemically modified graphene: methods and applications journal January 2011
Mesoporous Metal Oxide Graphene Nanocomposite Materials patent-application November 2012
Graphene-Based Ultracapacitors journal October 2008
Volatile Chemical Substance Catching Device and Electronic Apparatus patent-application November 2009
Process for producing nano graphene reinforced composite particles for lithium battery electrodes patent-application July 2010
Low-Temperature Solution Processing of Graphene−Carbon Nanotube Hybrid Materials for High-Performance Transparent Conductors journal May 2009
Mechanically Strong, Electrically Conductive, and Biocompatible Graphene Paper journal July 2008
Surface-Mediated Growth of Transparent, Oriented, and Well-Defined Nanocrystalline Anatase Titania Films journal October 2006
Nanowire structures comprising carbon patent-application September 2007
Nano graphene reinforced nanocomposite particles for lithium battery electrodes patent-application June 2010
Tin Nanoparticle Loaded Graphite Anodes for Li-Ion Battery Applications journal January 2004
Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks journal November 1998
Solution Properties of Graphite and Graphene journal June 2006
Nanostructured bulk thermoelectric material patent December 2007
Carbon-coated mesoporous silica with hydrophobicity and electrical conductivity journal January 2008
Li-ion batteries from LiFePO4 cathode and anatase/graphene composite anode for stationary energy storage journal March 2010
The Cycling Performance of Graphite Electrode Coated with Tin Oxide for Lithium Ion Battery [리튬이온전지용 주석산화물이 도포된 흑연전극의 싸이클 성능] journal May 2002
Low-temperature method of producing nano-scaled graphene platelets and their nanocomposites patent-application October 2008
Template-Free Synthesis of SnO2 Hollow Nanostructures with High Lithium Storage Capacity journal September 2006
Electron Transfer Kinetics of Aquated Fe[sup +3∕+2], Eu[sup +3∕+2], and V[sup +3∕+2] at Carbon Electrodes journal January 1993
Self-Assembly of a Nonionic Surfactant at the Graphite/Ionic Liquid Interface journal August 2005
Structural evolution during the reaction of Li with nano-sized rutile type TiO2 at room temperature journal February 2007
Self Assembled Multi-Layer Nanocomposite of Graphene and Metal Oxide Materials patent-application February 2011
Self-organizing high-density single-walled carbon nanotube arrays from surfactant suspensions journal August 2004
Biomimetic Pathways for Assembling Inorganic Thin Films journal August 1996
Development of Low Cost Carbonaceous Materials for Anodes in Lithium-Ion Batteries for Electric and Hybrid Electric Vehicles report December 2002
Crystal Phase Control for Titanium Dioxide Films by Direct Deposition in Aqueous Solutions journal February 2002
Graphene-based composite materials journal July 2006
Nanocomposite of graphene and metal oxide materials patent-application April 2010
Specific surface area of carbon nanotubes and bundles of carbon nanotubes journal April 2001
Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate) journal January 2006
Electric Field Effect in Atomically Thin Carbon Films journal October 2004
Electrospun mesoporous molecular sieve fibers patent-application July 2004
Optimized Lithium Iron Phosphate for High-Rate Electrochemical Applications journal January 2004
Processable aqueous dispersions of graphene nanosheets journal January 2008

Similar Records

Related Subjects