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Title: Nanoengineered membrane electrode assembly interface

Patent ·
OSTI ID:1089405

A membrane electrode structure suitable for use in a membrane electrode assembly (MEA) that comprises membrane-affixed metal nanoparticles whose formation is controlled by a photochemical process that controls deposition of the metal nanoparticles using a photocatalyst integrated with a polymer electrolyte membrane, such as an ionomer membrane. Impregnation of the polymer membrane with the photocatalyst prior to metal deposition greatly reduces the required amount of metal precursor in the deposition reaction solution by restricting metal reduction substantially to the formation of metal nanoparticles affixed on or near the surface of the polymer membrane with minimal formation of metallic particles not directly associated with the membrane.

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-94AL85000
Assignee:
Sandia Corporation (Albuquerque, NM)
Patent Number(s):
8,501,366
Application Number:
12/487,391
OSTI ID:
1089405
Country of Publication:
United States
Language:
English

References (20)

Reductive precipitation of metals photosensitized by tin and antimony porphyrins patent September 2003
Method of forming robust metal, metal oxide, and metal alloy layers on ion-conductive polymer membranes patent January 2004
Self-assembling multi-layer Pd nanoparticles onto Nafion™ membrane to reduce methanol crossover journal July 2005
Gas diffusion electrode for membrane fuel cells and method of its production patent January 1999
Study of Pt Electrode/Nafion Ionomer Interface in HClO[sub 4] by In Situ Surface-Enhanced FTIR Spectroscopy journal January 2006
Modification of polymer electrolyte membranes for DMFCs using Pd films formed by sputtering journal April 2002
Catalyst layer for polymer electrolyte fuel cells patent December 2000
Controlled Synthesis of 2-D and 3-D Dendritic Platinum Nanostructures journal January 2004
Materials and processes for providing fuel cells and active membranes patent June 2002
Dendritic metal nanostructures patent May 2008
Preparing in situ electrocatalytic films in solid polymer electrolyte membranes, composite microelectrode structures produced thereby and chloralkali process utilizing the same patent September 1990
Photocatalytic methods for preparation of electrocatalyst materials patent-application November 2006
Precipitation of Metallic Platinum into Nafion Ionomer Membranes: I . Experimental Results journal May 1993
Pd electroless plated Nafion® membrane for high concentration DMFCs journal August 2005
Membrane electrode unit for polymer electrolyte fuel cells and a process for the production thereof patent September 2008
Photocatalytic Methods for Preparation of Electrocatalyst Materials patent-application January 2009
Fabrication and Performance of Polymer Electrolyte Fuel Cells by Self-Assembly of Pt Nanoparticles journal January 2005
Dendritic Metal Nanostructures for Fuel Cells and Other Applications patent-application October 2007
Electrostatic self-assembly Pd particles on Nafion™ membrane surface to reduce methanol crossover journal February 2005
In Situ Electrode Formation on a Nafion Membrane by Chemical Platinization journal January 1992