skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Method for synthesis of high quality graphene

Patent ·
OSTI ID:1039209

A method is described herein for the providing of high quality graphene layers on silicon carbide wafers in a thermal process. With two wafers facing each other in close proximity, in a first vacuum heating stage, while maintained at a vacuum of around 10.sup.-6 Torr, the wafer temperature is raised to about 1500.degree. C., whereby silicon evaporates from the wafer leaving a carbon rich surface, the evaporated silicon trapped in the gap between the wafers, such that the higher vapor pressure of silicon above each of the wafers suppresses further silicon evaporation. As the temperature of the wafers is raised to about 1530.degree. C. or more, the carbon atoms self assemble themselves into graphene.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-05CH11231
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Number(s):
8,142,754
Application Number:
13/043,329
OSTI ID:
1039209
Country of Publication:
United States
Language:
English

References (25)

Thermodynamics and Kinetics of Graphene Growth on SiC(0001) journal March 2009
Self-doping effects in epitaxially grown graphene journal December 2008
Band Structure of Graphite journal January 1958
Room-Temperature Quantum Hall Effect in Graphene journal March 2007
Growth of 6H and 4H–SiC by sublimation epitaxy journal February 1999
Two-dimensional gas of massless Dirac fermions in graphene journal November 2005
Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide journal February 2009
Substrate-induced bandgap opening in epitaxial graphene journal September 2007
Synthesis and characterization of atomically thin graphite films on a silicon carbide substrate journal September 2006
Homogeneous large-area graphene layer growth on 6 H -SiC(0001) journal December 2008
Quasiparticle dynamics in graphene journal December 2006
Step-bunching in 6H-SiC growth by sublimation epitaxy journal November 1999
Interlayer Interaction and Electronic Screening in Multilayer Graphene Investigated with Angle-Resolved Photoemission Spectroscopy journal May 2007
Pit formation during graphene synthesis on SiC(0001): In situ electron microscopy journal June 2008
The rise of graphene journal March 2007
Ultraflat graphene journal November 2009
Detection of individual gas molecules adsorbed on graphene journal July 2007
Angle-resolved photoemission studies of the cuprate superconductors journal April 2003
Large-scale pattern growth of graphene films for stretchable transparent electrodes journal January 2009
Giant Intrinsic Carrier Mobilities in Graphene and Its Bilayer journal January 2008
Electric Field Effect in Atomically Thin Carbon Films journal October 2004
Ultrathin Epitaxial Graphite:  2D Electron Gas Properties and a Route toward Graphene-based Nanoelectronics journal December 2004
The Band Theory of Graphite journal May 1947
Spin qubits in graphene quantum dots journal February 2007
Growth mechanism for epitaxial graphene on vicinal 6 H -SiC ( 0001 ) surfaces: A scanning tunneling microscopy study journal July 2009

Related Subjects