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Title: Effect of Produced HCl during the Catalysis on Micro- and Mesoporous MOFs

Abstract

This communication reports the influence of alkylation reaction byproducts, particularly HCl, on MOF-5 with unusual structural transformation to starting precursor and yet maintaining the great catalytic activity in terms of high conversion and selectivity towards the less bulky para-oriented products.

Authors:
; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
Sponsoring Org.:
USDOE
OSTI Identifier:
989428
Report Number(s):
PNNL-SA-70760
Journal ID: ISSN 1528-7483; XW839C; 35599; KC0201050; TRN: US201019%%432
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
Crystal Growth & Design, 10(9):4118-4122
Additional Journal Information:
Journal Volume: 10; Journal Issue: 9; Journal ID: ISSN 1528-7483
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALKYLATION; CATALYSIS; HYDROCHLORIC ACID; CATALYSTS; MORPHOLOGICAL CHANGES; Environmental Molecular Sciences Laboratory

Citation Formats

Fernandez, Carlos A, Thallapally, Praveen K, Liu, J, and Peden, Charles HF. Effect of Produced HCl during the Catalysis on Micro- and Mesoporous MOFs. United States: N. p., 2010. Web. doi:10.1021/cg100796e.
Fernandez, Carlos A, Thallapally, Praveen K, Liu, J, & Peden, Charles HF. Effect of Produced HCl during the Catalysis on Micro- and Mesoporous MOFs. United States. https://doi.org/10.1021/cg100796e
Fernandez, Carlos A, Thallapally, Praveen K, Liu, J, and Peden, Charles HF. 2010. "Effect of Produced HCl during the Catalysis on Micro- and Mesoporous MOFs". United States. https://doi.org/10.1021/cg100796e.
@article{osti_989428,
title = {Effect of Produced HCl during the Catalysis on Micro- and Mesoporous MOFs},
author = {Fernandez, Carlos A and Thallapally, Praveen K and Liu, J and Peden, Charles HF},
abstractNote = {This communication reports the influence of alkylation reaction byproducts, particularly HCl, on MOF-5 with unusual structural transformation to starting precursor and yet maintaining the great catalytic activity in terms of high conversion and selectivity towards the less bulky para-oriented products.},
doi = {10.1021/cg100796e},
url = {https://www.osti.gov/biblio/989428}, journal = {Crystal Growth & Design, 10(9):4118-4122},
issn = {1528-7483},
number = 9,
volume = 10,
place = {United States},
year = {Wed Sep 01 00:00:00 EDT 2010},
month = {Wed Sep 01 00:00:00 EDT 2010}
}