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Title: Report of 1,000 Hour Catalyst Longevity Evaluation

This report presents the results of a 1,000 hour, high-pressure, catalyst longevity test for the decomposition of concentrated sulfuric acid. The reaction is used for both the sulfur-iodine (S-I) cycle and hybrid sulfur cycle. By the time of the delivery date of April 17, 2009, for project milestone no. 2NIN07TC050114, the 1% Pt/TiO2 catalyst had been in the reaction environment for 658 hours. During the first 480 hours of testing, the catalyst activity provided stable, near-equilibrium yields of 46.8% SO2 and 22.8% O2. However, product yields declined at sample exposure times >480 hours. At 658 hours of operation, catalyst activity (based on oxygen yield) declined to 57% relative to the stable period of catalyst activity. Thus, as of April 17, this catalyst did not provide the desired stability level of <10% degradation per 1,000 hours. The experiment was terminated on April 27, after 792 hours, when a fitting failed and the catalyst was displaced from the reactor such that the sample could not be recovered. Oxygen conversion at the end of the experiment was 12.5% and declining, suggesting that at that point, catalyst activity had decreased to 54% of the initial level.
Authors:
Publication Date:
OSTI Identifier:
966164
Report Number(s):
INL/EXT-09-16048
TRN: US200921%%387
DOE Contract Number:
DE-AC07-99ID-13727
Resource Type:
Technical Report
Research Org:
Idaho National Laboratory (INL)
Sponsoring Org:
DOE - NE
Country of Publication:
United States
Language:
English
Subject:
08 HYDROGEN; CATALYSTS; EVALUATION; OXYGEN; STABILITY; SULFUR CYCLE; SULFURIC ACID; TESTING catalyst; longevity; sulfuric acid