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Title: Reversible uptake of COS, CS2 and SO2; Ionic liquids with O-alkylxanthate, O-alkylthiocarbonate, and O-alkylsulfite anions

Journal Article · · Chemistry - a European Journal, 15(31):7619-7627

Further development of CO2 binding organic liquids to capture and release carbonyl sulfide, carbon disulfide and sulfur dioxide. This paper investigates a brand new class of ionic liquids which have potential as chemical sensors for acid gas capture. Applications to flue gas scrubbing are discussed with an emphasis on capture and release of COS, CS2 and SO2 with amidine and guanidine bases with alcohols. Formal spectroscopic characterization is presented.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
965545
Report Number(s):
PNNL-SA-62088; TRN: US200920%%329
Journal Information:
Chemistry - a European Journal, 15(31):7619-7627, Vol. 15, Issue 31
Country of Publication:
United States
Language:
English