skip to main content

Title: The Antimony-Based Type I Clathrate compounds Cs8Cd18Sb28 and Cs8Zn18Sb28**

The title compounds lie in a new region of phase space for such a structure, and have stoichiometries in accord with a classical Zintl phase formulation. The small semiconductor gaps indicated by DFT calculations are also supported by their diamagnetic susceptibilities.
Authors:
; ; ; ; ;
Publication Date:
OSTI Identifier:
963977
Report Number(s):
IS-J 7505
Journal ID: 1521-3773; TRN: US200918%%420
DOE Contract Number:
DE-AC02-07CH11358
Resource Type:
Journal Article
Resource Relation:
Journal Name: Angewandte Chemie; Journal Volume: 48; Journal Issue: 29
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; CLATHRATES; PHASE SPACE; CHEMISTRY