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Title: Potassium dicyanoargentate(I) 1,4,7,10,13,16-hexaoxacyclooctadecane.

The crystal structure of the title compound, K[Ag(CN){sub 2}]{center_dot}C{sub 12}H{sub 24}O{sub 6}, conventionally denoted K(18-crown-6)Ag(CN){sub 2}, where 18-crown-6 is 1,4,7,10,13,16-hexaoxacyclooctadecane, is characterized by closely packed linear chains formed by the coordination of the nitrile N atoms of the [Ag(CN){sub 2}]{sup -} anions to the K{sup +} cations. The K atoms lie on centers of inversion and are additionally bound to the six O atoms of the crown ether.
Authors:
; ;
Publication Date:
OSTI Identifier:
961432
Report Number(s):
ANL/MSD/JA-47715
Journal ID: ISSN 0108-2701; ACSCEE; TRN: US201012%%1495
DOE Contract Number:
DE-AC02-06CH11357
Resource Type:
Journal Article
Resource Relation:
Journal Name: Acta Crystallogr. C; Journal Volume: 59; Journal Issue: 2003
Research Org:
Argonne National Laboratory (ANL)
Sponsoring Org:
SC
Country of Publication:
United States
Language:
ENGLISH
Subject:
36 MATERIALS SCIENCE; ANIONS; ATOMS; CATIONS; CROWN ETHERS; CRYSTAL STRUCTURE; NITRILES; ORGANIC COMPOUNDS; POTASSIUM