Solid-state ligand dynamics in interpenetrating Mn[N(CN){sub 2}]{sub 2}(pyrazine) : a neutron spectroscopy study.
We have used quasielastic neutron scattering to probe the solid-state ligand dynamics in the coordination polymer Mn[N(CN){sub 2}]{sub 2}(pyz) (pyz = pyrazine) which has double-interpenetrating 3D lattices. A reversible structural phase transition occurs at 410 K as shown by neutron spectroscopy and differential scanning calorimetry. The origin of this transition is linked to rotational dynamics associated with the bridging pyz ligands. At 425 K, the pyrazine ring motion can be solely regarded as a 180 degree reorientational jump about the axis defined by the Mn-N coordinative bonds, occurring with a correlation time of 70 ps. This model can be extended to the 200-410 K temperature region using high-resolution backscattering spectroscopy to measure an identical motion on the time scale of nanoseconds with an activation energy of 24 {+-} 2 kJ mol-1. In contrast, no quasielastic scattering is seen for the 2D layered variant {beta}-Cu[N(CN){sub 2}]{sub 2}(pyz), owing to its more compact layer packing motif. Importantly, this work represents the very first study of solid-state rotational dynamics in an interpenetrating lattice structure.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- DE-AC02-06CH11357
- OSTI ID:
- 949418
- Report Number(s):
- ANL/MSD/JA-40749; JACSAT; TRN: US1003524
- Journal Information:
- J. Am. Chem. Soc., Vol. 124, Issue 42 ; Oct. 23, 2002; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- ENGLISH
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