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Title: Thermodynamic Model for Fluid-Fluid Interfacial Areas in Porous Media for Arbitrary Drainage-Imbibition Sequences

Fluid/fluid interfacial areas are important in controlling the rate of mass and energy transfer between fluid phases in porous media. We present a modified thermodynamically based model (TBM) to predict fluid/fluid interfacial areas in porous media for arbitrary drainage/imbibition sequences. The TBM explicitly distinguishes between interfacial areas associated with continuous (free) and isolated (entrapped) nonwetting fluids. The model is restricted to two-fluid systems in which (1) no significant conversion of mechanical work into heat occurs, (2) the wetting fluid completely wets the porous medium’s solid surfaces, and (3) no changes in interfacial area due to mass transfer between phases occur. We show example calculations for two different drainage/imbibition sequences in two porous media: a highly uniform silica sand and a well-graded silt. The TBM’s predictions for interfacial area associated with free nonwetting-fluid are identical to those of a previously published geometry-based model (GBM). However, predictions for interfacial area associated with entrapped nonwetting-fluid are consistently larger in the TBM than in the GBM. Although a comparison of model predictions with experimental data is currently only possible to a limited extent, good general agreement was found for the TBM. As required model parameters are commonly used as inputs for or tracked duringmore » multifluid-flow simulations, the modified TBM may be easily incorporated in numerical codes.« less
Authors:
; ; ;
Publication Date:
OSTI Identifier:
947466
Report Number(s):
PNNL-SA-60164
25393; 830403000; TRN: US200909%%97
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Vadose Zone Journal, 7(3):966-971; Journal Volume: 7; Journal Issue: 3
Research Org:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; ENERGY TRANSFER; MASS TRANSFER; SAND; SILICA; SILT; THERMODYNAMICS; INTERFACES; DRAINAGE; FLUIDS; POROUS MATERIALS; MATHEMATICAL MODELS 1/29/09 corrected title LRK; Environmental Molecular Sciences Laboratory