Etching and aging effects in nanosize Au clusters investigated using high resolution size-exclusion chromatography.
Journal Article
·
· Proposed for publication in Journal of Physical Chemistry B.
OSTI ID:946992
Experiments using high-resolution size exclusion chromatography (HRSEC), dynamic light scattering, and transmission electron microscopy are conducted to investigate the effects of aging of Au nanoclusters in the presence of surfactant ligands. It is observed that contrary to the expectation that aging in solution will always broaden the size dispersion and increase the average size (Ostwald ripening), a narrowing of the size dispersion and change in average size can occur with time under ambient conditions.
- Research Organization:
- Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC04-94AL85000
- OSTI ID:
- 946992
- Report Number(s):
- SAND2003-2316J; TRN: US200904%%301
- Journal Information:
- Proposed for publication in Journal of Physical Chemistry B., Journal Name: Proposed for publication in Journal of Physical Chemistry B.
- Country of Publication:
- United States
- Language:
- English
Similar Records
Au
130−
x
Ag
x
Nanoclusters with Non‐Metallicity: A Drum of Silver‐Rich Sites Enclosed in a Marks‐Decahedral Cage of Gold‐Rich Sites
Au 130− x Ag x Nanoclusters with Non‐Metallicity: A Drum of Silver‐Rich Sites Enclosed in a Marks‐Decahedral Cage of Gold‐Rich Sites
Deposition of metal clusters on single-layer graphene/Ru(0001): Factors that govern cluster growth
Journal Article
·
Fri Nov 08 00:00:00 EST 2019
· Angewandte Chemie
·
OSTI ID:946992
+6 more
Au 130− x Ag x Nanoclusters with Non‐Metallicity: A Drum of Silver‐Rich Sites Enclosed in a Marks‐Decahedral Cage of Gold‐Rich Sites
Journal Article
·
Fri Nov 08 00:00:00 EST 2019
· Angewandte Chemie (International Edition)
·
OSTI ID:946992
+6 more
Deposition of metal clusters on single-layer graphene/Ru(0001): Factors that govern cluster growth
Journal Article
·
· Surface Science
·
OSTI ID:946992