Spin-orbit holds the heavyweight title for Pu and Am: Exchange regains it for Cm
The conclusions of this paper are: (1) The 5f electrons in Cm are near an LS coupling scheme. (2) This coupling scheme allows for a large spin polarization of the 5f electrons, which in turn stabilizes the Cm III crystal structure. (3) Results for Cm show us the recipe for magnetic stabilization of the crystal structure of metals: (A) The metal must be near the itinerant-localized transition where multiple crystal structures have close energies; (B) The metal is just on the magnetic side of the transition; and (C) There must be a magnetic moment large enough to overcome the energy difference between crystal structures, thus dictating the atomic geometry. (4) These results solidify our understanding of magnetically-stabilized metals, showing us where to look for engineered materials with magnetic applications.
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- Conference: Presented at: Pu Futures 2008, Dijon, France, Jul 07 - Jul 11, 2008
- Research Org:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA
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- Country of Publication:
- United States
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CRYSTAL STRUCTURE; ELECTRONS; GEOMETRY; MAGNETIC MOMENTS; POLARIZATION; SPIN; STABILIZATION
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