Synthesis and stabilization of selenium nanoparticles on cellulose nanocrystal

Journal Article · Wed Aug 01 00:00:00 EDT 2007 · Materials Letters, 61(21):4297-4300

DOI:https://doi.org/10.1016/j.matlet.2007.01.091· OSTI ID:915702

Shin, Yongsoon; Blackwood, Jade M; Bae, In-Tae; Arey, Bruce W; Exarhos, Gregory J

Selenium nanoparticles of 10-20 nm in diameter have been prepared using cellulose nanocrystal (CNXL) as a reducing and structure-directing agent under hydrothermal conditions. Na2SeO3 was reduced to form elemental selenium nanoparticles under hydrothermal conditions. During the hydrothermal process (120-160 oC), CNXL rods were mainly maintained and selenium nanoparticles were interfacially bound to CNXL surface. The reaction temperature affects the sizes of interfacially bound selenium nanoparticles. X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), and transmission electron microscope (TEM) were employed to characterize interfacially bound selenium nanoparticles on CNXL surface.

• Research Organization: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
• Sponsoring Organization: USDOE
• DOE Contract Number: AC05-76RL01830
• OSTI ID: 915702
• Report Number(s): PNNL-SA-51883; MLETDJ; KC0201050; TRN: US200816%%33
• Journal Information: Materials Letters, 61(21):4297-4300, Vol. 61, Issue 21; ISSN 0167-577X
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CELLULOSE
NANOSTRUCTURES
SELENIUM
STABILIZATION
SYNTHESIS
Selenium
Cellulose nanocrystal
Nanomaterials
Surface reduction