Laboratory-Scale Column Testing Using IONSIV IE-911 for Removing Cesium from Acidic Tank Waste Simulant. 1: Cesium Exchange Capacity of a 15-cm3 Column and Dynamic Stability of the Exchange Media
Bench-scale column tests were performed using a commercial form of crystalline silicotitanate (CST) for removing radio-cesium from a surrogate acidic tank solution representative of liquid waste stored at the Idaho National Engineering and Environmental Laboratory (INEEL). An engineered form of CST ion exchanger, known as IONSIVtm IE-911 (UOP, Mt Laurel, NJ, USA), was tested in 15 cm3 columns at a flow rate of 5 bed volumes per hour. These experiments showed the ion exchange material to have reasonable selectivity and capacity for removing cesium from the complex chemical matrix of the solution. However, previous testing indicated that partial neutralization of the feed stream was necessary to increase the stability of the ion exchange media. Thus, in these studies, CST degradation was determined as a function of throughput in order to better assess the stability characteristics of the exchanger for potential future waste treatment applications. Results of these tests indicate that the degradation of the CST reaches a maximum very soon after the acidic feed is introduced to the column and then rapidly declines. Total dissolution of bed material did not exceed 3% under the experimental regime used.
- Research Organization:
- Idaho National Lab. (INL), Idaho Falls, ID (United States)
- Sponsoring Organization:
- DOE - EM
- DOE Contract Number:
- DE-AC07-99ID-13727
- OSTI ID:
- 912393
- Report Number(s):
- INEEL/JOU-04-02477; TRN: US0800370
- Journal Information:
- Solvent Extraction & Ion Exchange, Vol. 23, Issue 4; ISSN 0736-6299
- Country of Publication:
- United States
- Language:
- English
Similar Records
The Effect of Pressure and Organic Constituents on the Cesium Ion Exchange Performance of IONSIV IE-911
Removal of Cesium From Acidic Radioactive Tank Waste Using IONSIV IE-911 (CST)