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Title: PHYSICAL AND CHEMICAL MEASUREMENTS NEEDED TO SUPPORT DISPOSITION OFSAVANNAH RIVER SITE RADIOACTIVE HIGH LEVEL WASTE SLUDGE

Radioactive high level waste (HLW) sludge generated as a result of decades of production and manufacturing of plutonium, tritium and other nuclear materials is being removed from storage tanks and processed into a glass waste-form for permanent disposition at the Federal Repository. Characterization of this HLW sludge is a prerequisite for effective planning and execution of sludge disposition activities. The radioactivity of HLW makes sampling and analysis of the sludge very challenging, as well as making opportunities to perform characterization rare. In order to maximize the benefit obtained from sampling and analysis, a recommended list of physical property and chemical measurements has been developed. This list includes distribution of solids (insoluble and soluble) and water; densities of insoluble solids, interstitial solution, and slurry rheology (yield stress and consistency); mineral forms of solids; and primary elemental and radioactive constituents. Sampling requirements (number, type, volume, etc.), sample preparation techniques, and analytical methods are discussed in the context of pros and cons relative to end use of the data. Generation of useful sample identification codes and entry of results into a centralized database are also discussed.
Authors:
Publication Date:
OSTI Identifier:
907771
Report Number(s):
LWO-PIT-2007-00058
TRN: US0703299
DOE Contract Number:
DE-AC09-96SR18500
Resource Type:
Conference
Resource Relation:
Conference: Materials Science and Technology Conference
Publisher:
pubinfo
Research Org:
SRS
Sponsoring Org:
DOE
Country of Publication:
United States
Language:
English
Subject:
12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; HIGH-LEVEL RADIOACTIVE WASTES; VITRIFICATION; SAMPLE PREPARATION; SAMPLING; SLUDGES; CHEMICAL ANALYSIS; PHYSICAL PROPERTIES