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Title: Surface modification of nickel based alloys for improved oxidation resistance

Conference ·
OSTI ID:901108

The present research is aimed at the evaluation of a surface modification treatment to enhance the high temperature stability of nickel-base superalloys. A low Coefficient Thermal Expansion (CTE ~12.5x10-6/°C) alloy based on the composition (in weight %) of Ni-22Mo-12.5Cr was produced by Vacuum Induction Melting and Vacuum Arc Melting and reduced to sheet by conventional thermal-mechanical processing. A surface treatment was devised to enhance the oxidation resistance of the alloys at high temperature. Oxidation tests (in dry and wet air; treated and untreated) were conducted 800°C to evaluate the oxidation resistance of the alloys. The results were compared to the behavior of Haynes 230 (Ni-22Cr) in the treated and untreated conditions. The treatment was not very effective for Haynes 230, as this alloy had similar oxidation behavior in both the treated and untreated conditions. However, the treatment had a significant effect on the behavior of the low CTE alloy. At 800°C, the untreated Ni-12.5Cr alloy was 5 times less oxidation resistant than Haynes 230. However, in the treated condition, the Ni-12.5Cr alloy had comparable oxidation resistance to the Haynes 230 alloy.

Research Organization:
Albany Research Center (ARC), Albany, OR (United States)
Sponsoring Organization:
USDOE - Office of Fossil Energy (FE)
OSTI ID:
901108
Report Number(s):
DOE/ARC-2005-086; TRN: US200714%%69
Resource Relation:
Conference: Superalloys and Coatings for High Temperature Applications, a symposium held at the 134th TMS Annual Meeting, San Francisco, CA, February 13-17, 2005 (TMS, The Minerals, Metals and Materials Society)
Country of Publication:
United States
Language:
English