High Precision Density Measurements of Single Particles: The Density of Metastable Phases
We describe a system designed to measure the size, composition and density of individual particles in real-time. It uses a DMA to select a monodisperse particle population and the single particle mass spectrometer to measure individual particle mass spectrometer to measure individual particle aerodynamic diameter and composition. Mobility and aerodynamic diameters are used to extract particle density. The addition of individual particle density to the mass spectrum is intended to improve the data classification process. In the present paper we demonstrate that the system has the requisite accuracy and resolution to make this approach practicable. We also present a high precision variant that uses an internal calibrant to remove any of the systematic errors and significantly improves the measurement quality. The high precision scheme is most suitable for laboratory studies making it possible to follow slight changes in particle density. An application of the system to measure the density of hygroscopic particles of atmospheric importance in metastable phases near zero relative humidity is presented. The density data are consistent with conclusions reached in a number of other studies that some particle systems of atmospheric significance once deliquesced persist as droplets down to near zero relative humidity.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 876893
- Report Number(s):
- PNNL-SA-44016; ASTYDQ; 17498; KC0302020; TRN: US200611%%269
- Journal Information:
- Aerosol Science and Technology, 39(10):972-986, Vol. 39, Issue 10; ISSN 0278-6826
- Country of Publication:
- United States
- Language:
- English
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