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Title: Discovery of Critical Oxygen Content for Glass Formation in Zr80Pt20 Melt Spun Ribbons

Zr{sub 80}Pt{sub 20} alloys may form meta-stable quasicrystals either during devitrification of an amorphous phase or directly upon cooling from a liquid depending on processing conditions. To date, little attention has been given to the role of oxygen on the glass formation or devitrification behavior of Zr-Pt and similar alloys. This study reveals that oxygen content during melt spinning indeed strongly influences the formation of the as-quenched structure. A critical amount of oxygen was found to be required to form amorphous ribbons at a fixed quench rate. At lower oxygen levels (i.e., <500 ppm mass), a fully crystallized is formed; the structure is composed mainly of meta-stable {beta}-Zr with a small fraction of a quasicrystalline phase. At higher oxygen levels, the as-quenched structure transitions to a fully amorphous structure ({approx}1000 ppm mass), and with further oxygen addition forms a mixture of amorphous and quasicrystalline ({approx}1500 ppm mass) or crystalline phases (>2500 ppm mass). Details regarding the structure of the meta-stable {beta}-Zr phase in the low-oxygen ribbons are provided along with a discussion of the structural similarity between this phase and the quasicrystal structure that formed in this alloy.
Authors:
; ; ;
Publication Date:
OSTI Identifier:
832898
Report Number(s):
IS-M 926
TRN: US200430%%985
DOE Contract Number:
W-7405-Eng-82
Resource Type:
Conference
Resource Relation:
Conference: Conference title not supplied, Conference location not supplied, Conference dates not supplied; Other Information: PBD: 30 Sep 2004
Research Org:
Ames Laboratory, Ames, IA (US)
Sponsoring Org:
USDOE Office of Science (SC) (US)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ALLOYS; GLASS; MIXTURES; OXYGEN; OXYGEN ADDITIONS; PROCESSING