Design and evaluation of a solid sampler for the monitoring of airborne 1,6-hexamethylene diisocyanate (HDI) and its prepolymers in two-component spray painting

Journal Article · Sun Mar 01 00:00:00 EST 1992 · American Industrial Hygiene Association Journal; (United States)

DOI:https://doi.org/10.1080/15298669291359447· OSTI ID:7161401

Huynh, C K; Vu-Duc, T; Savolainen, H ^[1]

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1. Institut Universitaire de Medecine et d'Hygiene du Travail, Universite de Lausanne, (Switzerland)

An active, solvent-free solid sampler was developed for the collection of 1,6-hexamethylene diisocyanate (HDI) aerosol and prepolymers. The sampler was made of a filter impregnated with 1-(2-methoxyphenyl)piperazine contained in a filter holder. Interferences with HDI were observed when a set of cellulose acetate filters and a polystyrene filter holder were used; a glass fiber filter and polypropylene filter cassette gave better results. The applicability of the sampling and analytical procedure was validated with a test chamber, constructed for the dynamic generation of HDI aerosol and prepolymers in commercial two-component spray paints (Desmodur N75) used in car refinishing. The particle size distribution, temporal stability, and spatial uniformity of the simulated aerosol were established in order to test the sampler. The monitoring of aerosol concentrations was conducted with the solid sampler paired to the reference impinger technique (impinger flasks contained 10 mL of 0.5 mg/mL 1-(2-methoxyphenyl)piperazine in toluene) under a controlled atmosphere in the test chamber. Analyses of derivatized HDI and prepolymers were carried out by using high-performance liquid chromatography and ultraviolet detection. The correlation between the solvent-free and the impinger techniques appeared fairly good (Y = 0.979X-0.161; R = 0.978), when the tests were conducted in the range of 0.1 to 10 times the threshold limit value (TLV) for HDI monomer and up to 60 micrograms/m3 (3 U.K. TLVs) for total -N=C=O groups.

• OSTI ID: 7161401
• Journal Information: American Industrial Hygiene Association Journal; (United States), Vol. 53:3; ISSN 0002-8894
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
AIR SAMPLERS
DESIGN
ISOCYANATES
AIR POLLUTION MONITORING
AEROSOLS
AIR POLLUTION
AUTOMOBILES
ECOLOGICAL CONCENTRATION
FILTERS
PARTICLE SIZE
COLLOIDS
DISPERSIONS
EQUIPMENT
MONITORING
POLLUTION
SAMPLERS
SIZE
SOLS
VEHICLES
540120* - Environment
Atmospheric- Chemicals Monitoring & Transport- (1990-)