skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Photophysical degradation of poly(1-vinylnaphthalene) and poly(methyl methacrylate) blends

Abstract

A reversible photophysical degradation of P1VN/PMMA blends is observed at 77 K upon prolonged irradiation. In the dilute blends, the ratio of singlet excimer to monomer emission increases as exposure time increases. However, thermal annealing even below the glass transition temperature can restore the original ratio of singlet excimer to monomer.

Authors:
;  [1]
  1. Univ. of Michigan, Ann Arbor (USA)
Publication Date:
OSTI Identifier:
7140649
Resource Type:
Journal Article
Journal Name:
Journal of Physical Chemistry; (USA)
Additional Journal Information:
Journal Volume: 94:5; Journal ID: ISSN 0022-3654
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MIXTURES; PHOTOCHEMICAL REACTIONS; POLYMERS; ACRYLATES; DATA ANALYSIS; EXPERIMENTAL DATA; MEASURING INSTRUMENTS; MEASURING METHODS; NAPHTHALENE; PHOTOCHEMISTRY; AROMATICS; CARBOXYLIC ACID SALTS; CHEMICAL REACTIONS; CHEMISTRY; CONDENSED AROMATICS; DATA; DISPERSIONS; HYDROCARBONS; INFORMATION; NUMERICAL DATA; ORGANIC COMPOUNDS; 400500* - Photochemistry

Citation Formats

Li, Ching Shan, and Lopelman, R. Photophysical degradation of poly(1-vinylnaphthalene) and poly(methyl methacrylate) blends. United States: N. p., 1990. Web. doi:10.1021/j100368a073.
Li, Ching Shan, & Lopelman, R. Photophysical degradation of poly(1-vinylnaphthalene) and poly(methyl methacrylate) blends. United States. https://doi.org/10.1021/j100368a073
Li, Ching Shan, and Lopelman, R. 1990. "Photophysical degradation of poly(1-vinylnaphthalene) and poly(methyl methacrylate) blends". United States. https://doi.org/10.1021/j100368a073.
@article{osti_7140649,
title = {Photophysical degradation of poly(1-vinylnaphthalene) and poly(methyl methacrylate) blends},
author = {Li, Ching Shan and Lopelman, R},
abstractNote = {A reversible photophysical degradation of P1VN/PMMA blends is observed at 77 K upon prolonged irradiation. In the dilute blends, the ratio of singlet excimer to monomer emission increases as exposure time increases. However, thermal annealing even below the glass transition temperature can restore the original ratio of singlet excimer to monomer.},
doi = {10.1021/j100368a073},
url = {https://www.osti.gov/biblio/7140649}, journal = {Journal of Physical Chemistry; (USA)},
issn = {0022-3654},
number = ,
volume = 94:5,
place = {United States},
year = {Thu Mar 08 00:00:00 EST 1990},
month = {Thu Mar 08 00:00:00 EST 1990}
}