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Title: Compatibility of PWR gasket and packing materials and resins with organic amines

Technical Report ·
OSTI ID:7112260
;  [1];  [2]
  1. Adams and Hobart Consulting Engineers, Fremont, CA (United States)
  2. Balazs Analytical Lab., Mountain View, CA (United States)

The objectives of this testing program were two-fold: (1) to examine the compatibility of morpholine and five other amines with several synthetic polymeric materials useful for gaskets and seals in pressurized water reactor (PWR) secondary cycles and (2) to examine the potential chemical degradation of ion exchange (IX) resins by morpholine and ethanolamine. The screening of the polymeric materials in the amines was performed by heating small samples of the materials in the amines for one week to one month. Interaction of the amines with the materials was accelerated by testing at elevated temperatures and at high amine concentrations. Two materials (Kalrez and EPDM) that are potentially useful in high-temperature and high-pressure steam systems were tested in morpholine solutions in sealed bombs at 260{degrees}C (500{degrees}). After heating in the aqueous amine solutions, changes in weight were measured and the samples were visually examined for physical changes, such as swelling or cracking. Selected materials underwent testing for hardness, elongation, and tensile strength after heating in morpholine for one month. This document provides the results of this testing program.

Research Organization:
Electric Power Research Inst., Palo Alto, CA (United States); Adams and Hobart Consulting Engineers, Fremont, CA (United States)
Sponsoring Organization:
EPRI; Electric Power Research Inst., Palo Alto, CA (United States)
OSTI ID:
7112260
Report Number(s):
EPRI-TR-100794; TRN: 92-026853
Country of Publication:
United States
Language:
English