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Title: Mesoxalaldehyde acetals

Abstract

The treatment of methylglyoxal acetals by alkyl nitrites in the presence of the corresponding aliphatic alcohols and hydrochloric acid leads to the formation of linear mesoxalaldehyde acetals, whose structure was established by NMR spectroscopy and mass spectrometry. The major pathways for the decomposition of these molecules upon electron impact were established.

Authors:
; ; ; ;
Publication Date:
Research Org.:
Ufa Petroleum Institute (USSR)
OSTI Identifier:
6974916
Resource Type:
Journal Article
Journal Name:
J. Org. Chem. USSR (Engl. Transl.); (United States)
Additional Journal Information:
Journal Volume: 23:6; Other Information: Translated from Zh. Org. Khim.; 23: No. 6, 1158-1163(Jun 1987)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 74 ATOMIC AND MOLECULAR PHYSICS; ACETALS; IONIZATION; MASS SPECTRA; NMR SPECTRA; ALDEHYDES; CHEMICAL REACTION KINETICS; CHEMICAL SHIFT; COUPLING CONSTANTS; DISSOCIATION; ELECTRON BEAMS; ELECTRON-MOLECULE COLLISIONS; J-J COUPLING; MOLECULAR IONS; MOLECULAR STRUCTURE; STRUCTURAL CHEMICAL ANALYSIS; BEAMS; CHARGED PARTICLES; COLLISIONS; COUPLING; ELECTRON COLLISIONS; ETHERS; INTERMEDIATE COUPLING; IONS; KINETICS; LEPTON BEAMS; MOLECULE COLLISIONS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PARTICLE BEAMS; REACTION KINETICS; SPECTRA; 400201* - Chemical & Physicochemical Properties; 640302 - Atomic, Molecular & Chemical Physics- Atomic & Molecular Properties & Theory; 640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena

Citation Formats

Gordeeva, G N, Kalashnikov, S M, Popov, Yu N, Kruglov, E A, and Imashev, U B. Mesoxalaldehyde acetals. United States: N. p., 1987. Web.
Gordeeva, G N, Kalashnikov, S M, Popov, Yu N, Kruglov, E A, & Imashev, U B. Mesoxalaldehyde acetals. United States.
Gordeeva, G N, Kalashnikov, S M, Popov, Yu N, Kruglov, E A, and Imashev, U B. 1987. "Mesoxalaldehyde acetals". United States.
@article{osti_6974916,
title = {Mesoxalaldehyde acetals},
author = {Gordeeva, G N and Kalashnikov, S M and Popov, Yu N and Kruglov, E A and Imashev, U B},
abstractNote = {The treatment of methylglyoxal acetals by alkyl nitrites in the presence of the corresponding aliphatic alcohols and hydrochloric acid leads to the formation of linear mesoxalaldehyde acetals, whose structure was established by NMR spectroscopy and mass spectrometry. The major pathways for the decomposition of these molecules upon electron impact were established.},
doi = {},
url = {https://www.osti.gov/biblio/6974916}, journal = {J. Org. Chem. USSR (Engl. Transl.); (United States)},
number = ,
volume = 23:6,
place = {United States},
year = {Tue Nov 10 00:00:00 EST 1987},
month = {Tue Nov 10 00:00:00 EST 1987}
}