Surface photochemistry of phosgene on clean and iodine-covered Ag(111)
Journal Article
·
· Journal of Physical Chemistry; (USA)
- Univ. of Texas, Austin (USA)
The photochemistry of phosgene (Cl{sub 2}CO) on clean and partially iodine covered Ag(111) has been studied. Cl{sub 2}CO adsorbed on Ag(111) at 100 K desorbs molecularly with no detectable thermal decomposition. On clean Ag(111) K, UV photolysis occurs readily for both submonolayer and multilayer coverages. The photolysis products are chlorine, which remains on the surface, and CO, which desorbs during irradiation. There is no detectable photodesorption of molecular Cl{sub 2}CO.
- OSTI ID:
- 6807045
- Journal Information:
- Journal of Physical Chemistry; (USA), Vol. 94:6; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:6807045
Surface photochemistry: products retained on Pt(111) during photolysis of adsorbed CH/sub 3/Br
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+2 more
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
SILVER
SURFACE PROPERTIES
DATA ANALYSIS
EXPERIMENTAL DATA
MEASURING INSTRUMENTS
MEASURING METHODS
PHOSGENE
PHOTOCHEMISTRY
CARBONIC ACID DERIVATIVES
CHEMISTRY
DATA
ELEMENTS
INFORMATION
METALS
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
TRANSITION ELEMENTS
400500* - Photochemistry
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
SILVER
SURFACE PROPERTIES
DATA ANALYSIS
EXPERIMENTAL DATA
MEASURING INSTRUMENTS
MEASURING METHODS
PHOSGENE
PHOTOCHEMISTRY
CARBONIC ACID DERIVATIVES
CHEMISTRY
DATA
ELEMENTS
INFORMATION
METALS
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
TRANSITION ELEMENTS
400500* - Photochemistry