Novel palladium(II)-catalyzed copolymerization of carbon monoxide with olefins

Journal Article · Fri Jan 01 00:00:00 EST 1982 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00376a053· OSTI ID:6697422

Sen, A; Lai, T W

The catalyst, (Pd(CH/sub 3/CN)/sub 4/)(BF/sub 4/)/sub 2/.n-triphenylphosphine n = (1-3), demonstrated the capacity to mediate the copolymerization of CO with ethylene and other alkenes under very mild conditions. The reaction of ethylene (350 psi), dissolved in acetonitrile, and CO(350 psi) was performed at 25/sup 0/C for 1 d. The copolymerizations of CO(800 psi) with norbornadiene and norbornylene were performed at 60/sup 0/C. The structures of the copolymers were studied by NMR. 9 references, 1 figure.

• Research Organization: Pennsylvania State Univ., University Park
• DOE Contract Number: AC02-81ER10992
• OSTI ID: 6697422
• Journal Information: J. Am. Chem. Soc.; (United States), Vol. 104:12
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
10 SYNTHETIC FUELS
CARBON MONOXIDE
COPOLYMERIZATION
STRUCTURAL CHEMICAL ANALYSIS
ETHYLENE
NORBORNADIENE
PALLADIUM COMPLEXES
CATALYTIC EFFECTS
ACETONITRILE
BORON FLUORIDES
CATALYSTS
CHEMICAL REACTION YIELD
COMPARATIVE EVALUATIONS
COPOLYMERS
EXPERIMENTAL DATA
LOW PRESSURE
MEDIUM PRESSURE
MEDIUM TEMPERATURE
NMR SPECTRA
ORGANIC SOLVENTS
PHOSPHINES
PRESSURE DEPENDENCE
TIME DEPENDENCE
ALKENES
BORON COMPOUNDS
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKENES
DATA
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
INFORMATION
NITRILES
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
OXIDES
OXYGEN COMPOUNDS
PHOSPHORUS COMPOUNDS
POLYMERIZATION
POLYMERS
SOLVENTS
SPECTRA
TRANSITION ELEMENT COMPLEXES
YIELDS
400201* - Chemical & Physicochemical Properties
400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
090121 - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989)