Process for the reduction of nitrogen oxides in an effluent
A process is described for reducing the concentration of nitrogen oxides in an effluent from the combustion of a carbonaceous fuel, which process comprises injecting into the effluent ammonia and an enhancer selected from the group consisting of hexamethylenetetramine, a lower carbon alcohol, a hydroxyl amino hydrocarbon, sugar, furfural, furfural derivatives, an amino acid, a protein-containing composition, mixtures of ortho-, meta-, and para-methyl phenols, guanidine, guanidine carbonate, biguanidine, guanylurea sulfate, melamine, dicyandiamide, calcium cyanamide, biuret, 1,1'-azobisformamide, methylol urea, methylol urea-urea condensation product, dimethylol urea, methyl urea, dimethyl urea, and mixtures thereof, at an effluent temperature above about 1300/sup 0/F and a molar ratio of nitrogen in the ammonia and enhancer to the baseline nitrogen oxides level of about 1:5 to about 6:1 wherein the excess of oxygen in the effluent is no greater than about 6%.
- Assignee:
- Fuel Tech, Inc., Stamford, CT
- Patent Number(s):
- US 4770863
- OSTI ID:
- 6662468
- Resource Relation:
- Patent File Date: Filed date 13 Feb 1987
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
54 ENVIRONMENTAL SCIENCES
GASEOUS WASTES
DENITRATION
NITROGEN OXIDES
REMOVAL
AIR POLLUTION CONTROL
ALCOHOLS
AMIDES
AMINES
AMINO ACIDS
AMMONIA
CARBONATES
FURFURAL
GUANIDINES
HIGH TEMPERATURE
PHENOLS
PROTEINS
SACCHARIDES
UREA
ALDEHYDES
AROMATICS
CARBOHYDRATES
CARBON COMPOUNDS
CARBONIC ACID DERIVATIVES
CARBOXYLIC ACIDS
CHALCOGENIDES
CHEMICAL REACTIONS
CONTROL
FURANS
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
POLLUTION CONTROL
WASTES
010800* - Coal
Lignite
& Peat- Waste Management
500200 - Environment
Atmospheric- Chemicals Monitoring & Transport- (-1989)