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Title: Development of a portable field monitor for PCBs. Final report

With the advent of recent regulations and those yet pending concerning allowable concentrations of polychlorinated biphenyls (PCBs), personnel in all aspects of the electric power industry, analytical support personnel, and those in the regulatory functions themselves have realized that the PCB problem, as well as these associated regulations, has far surpassed available monitoring capability. In short, detailed, stringent regulations are being set for contamination levels where no accepted ASTM procedure or instrumentation exists. The largest PCB problems occur in the form of PCB-contaminated oil in field transformers and storage containers, and pure askarel in transformers and capacitors. The most immediate need for a portable field instrument would be for use under PCB spill conditions. Portable monitors based on the principles of photoionization detection (PID) and infrared spectroscopy (IR) have been adapted and evaluated for this purpose. The latter includes both flow cell and horizontal multiple internal reflectance (HMIR) sampling configurations. Extensive work has also been performed on solvent-solvent and solvent-soil extractions, as well as PCB adsorption on packings, for use under spill conditions.
Authors:
; ;
Publication Date:
OSTI Identifier:
6604238
Report Number(s):
EPRI-CS-2828
ON: DE83007425
DOE Contract Number:
W-7405-ENG-26
Resource Type:
Technical Report
Resource Relation:
Other Information: Portions are illegible in microfiche products
Research Org:
Oak Ridge National Lab., TN (USA)
Country of Publication:
United States
Language:
English
Subject:
02 PETROLEUM; 54 ENVIRONMENTAL SCIENCES; 20 FOSSIL-FUELED POWER PLANTS; AIR POLLUTION MONITORS; DESIGN; CHLORINATED AROMATIC HYDROCARBONS; MONITORING; ELECTRIC POWER INDUSTRY; HAZARDOUS MATERIALS SPILLS; INFRARED SPECTROMETERS; INSULATING OILS; PHOTOIONIZATION; AROMATICS; HALOGENATED AROMATIC HYDROCARBONS; INDUSTRY; IONIZATION; MEASURING INSTRUMENTS; MONITORS; OILS; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; OTHER ORGANIC COMPOUNDS; SPECTROMETERS 020900* -- Petroleum-- Environmental Aspects; 500200 -- Environment, Atmospheric-- Chemicals Monitoring & Transport-- (-1989); 200202 -- Fossil-Fueled Power Plants-- Waste Management-- Noxious Gas & Particulate Emissions