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Title: Electrode kinetics at a platinum anode in chloroacetic acid solutions

Abstract

It was shown by direct comparison of kinetic and adsorption data that at platinum in solutions of mono- and trichloroacetic acid, the anodic processes are entirely analogous in character to the processes occurring in acetate solutions. The lack of Kolbe electrosynthesis products in the electrolysis of chloroacetic acids is to the special reaction features of the secondary chloroalkyl radicals.

Authors:
;
Publication Date:
Research Org.:
A.N. Frumkin Institute of Electrochemistry, Moscow, USSR
OSTI Identifier:
6558545
Resource Type:
Journal Article
Journal Name:
Sov. Electrochem. (Engl. Transl.); (United States)
Additional Journal Information:
Journal Volume: 22:8; Other Information: Translated from Elektrokhimiya; 22: No. 8, 1029-1033(Aug 1986)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ACETATES; ELECTROLYSIS; OXIDATION; ACETIC ACID; ORGANIC CHLORINE COMPOUNDS; PLATINUM; CATALYTIC EFFECTS; ADSORPTION; CARBON DIOXIDE; CHEMICAL REACTION KINETICS; DESORPTION; ELECTROCATALYSTS; ELECTROCHEMISTRY; OVERVOLTAGE; OXYGEN; PH VALUE; POLARIZATION; POTENTIOMETRY; CARBON COMPOUNDS; CARBON OXIDES; CARBOXYLIC ACID SALTS; CARBOXYLIC ACIDS; CATALYSTS; CHALCOGENIDES; CHEMICAL REACTIONS; CHEMISTRY; ELEMENTS; KINETICS; LYSIS; METALS; MONOCARBOXYLIC ACIDS; NONMETALS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PLATINUM METALS; REACTION KINETICS; SORPTION; TITRATION; TRANSITION ELEMENTS; 400400* - Electrochemistry; 400201 - Chemical & Physicochemical Properties

Citation Formats

Lotvin, B M, and Vasil'ev, Yu B. Electrode kinetics at a platinum anode in chloroacetic acid solutions. United States: N. p., 1987. Web.
Lotvin, B M, & Vasil'ev, Yu B. Electrode kinetics at a platinum anode in chloroacetic acid solutions. United States.
Lotvin, B M, and Vasil'ev, Yu B. 1987. "Electrode kinetics at a platinum anode in chloroacetic acid solutions". United States.
@article{osti_6558545,
title = {Electrode kinetics at a platinum anode in chloroacetic acid solutions},
author = {Lotvin, B M and Vasil'ev, Yu B},
abstractNote = {It was shown by direct comparison of kinetic and adsorption data that at platinum in solutions of mono- and trichloroacetic acid, the anodic processes are entirely analogous in character to the processes occurring in acetate solutions. The lack of Kolbe electrosynthesis products in the electrolysis of chloroacetic acids is to the special reaction features of the secondary chloroalkyl radicals.},
doi = {},
url = {https://www.osti.gov/biblio/6558545}, journal = {Sov. Electrochem. (Engl. Transl.); (United States)},
number = ,
volume = 22:8,
place = {United States},
year = {Sun Feb 01 00:00:00 EST 1987},
month = {Sun Feb 01 00:00:00 EST 1987}
}