The stability and utility of diagnostic ratio hydrocarbon fingerprinting for soils contaminated with petroleum hydrocarbons
In order to recover costs for oil spill cleanup and restoration regulatory agencies and trustees of natural resources are interested in identifying parties responsible for hydrocarbon releases, and for associated environmental damages. Chemical analyses of contaminated soil and groundwater samples are currently used to identify the sources of contamination in soil and groundwater systems. However, conventional hydrocarbon fingerprinting approaches such as EPA Method 8015, EPA Method 8270, and ASTM Method 3328-91 afford a low resolution fingerprint that is easily degraded in the environment. The challenge to the hydrocarbon chemist is to develop an analytical approach that minimizes the impact of environmental weathering and biodegradation on the oil signature and improves the accuracy of oil source identification. An advanced chemical fingerprinting strategy is presented that combines sensitive and hydrocarbon specific analytical methods with a detailed interpretive strategy designed to minimize the impacts of environmental weathering and biodegradation. Data will be presented from a series of oil biodegradation studies in soil that clearly demonstrate the utility and stability of source ratio analysis over a wide range of oil degradation states and oil types. Using principal component analysis, stable source ratios of C[sub 3]-dibenzothiophenes/C[sub 3]-phenanthrenes, and C[sub 2]-dibenzothiophenes/C[sub 2]-phenanthrenes were identified and evaluated. These source ratios retain their characteristic source ratio signature even after 95 percent of the PAH and dibenzothiophene target analytes and 70 percent of the total oil has been biodegraded.
- OSTI ID:
- 6551479
- Report Number(s):
- CONF-960527-; CODEN: AABUD2
- Journal Information:
- AAPG Bulletin, Vol. 5; Conference: Annual convention of the American Association of Petroleum Geologists, Inc. and the Society for Sedimentary Geology: global exploration and geotechnology, San Diego, CA (United States), 19-22 May 1996; ISSN 0149-1423
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
02 PETROLEUM
HYDROCARBONS
ECOLOGICAL CONCENTRATION
OIL SPILLS
PATTERN RECOGNITION
SOILS
CONTAMINATION
ENVIRONMENTAL TRANSPORT
MASS TRANSFER
ORGANIC COMPOUNDS
540220* - Environment
Terrestrial- Chemicals Monitoring & Transport- (1990-)
020900 - Petroleum- Environmental Aspects
023000 - Petroleum- Properties & Composition