Electrolytic method for recovery of lead from scrap batteries: scale-up study using 20-liter multielectrode cell. Report of investigations/1984

Technical Report · Sun Jan 01 00:00:00 EST 1984

OSTI ID:6497922

Lee, A Y; Cole, Jr, E R; Paulson, D L

Anodes cast from scrap battery lead were electrorefined in a 20-L multielectrode cell for 3 to 7 days. The anodes, containing 2 to 2.5 pct antimony, were ideal for obtaining firm and adherent slime blankets. Cathode deposits, assaying 99.99 pct Pb, were obtained, with current efficiencies near 99 pct. Sludge leaching was done in 100-L tanks followed by filtering in 61 cm square vacuum pan filters. Lead of greater than 99.99-pct purity was recovered from the filtrate by electrowinning in a 20-L multielectrode cell using insoluble PbO2-Ti (lead dioxide-coated titanium) anodes and pure lead cathodes. The fluosilicic acid electrolyte depleted in lead was repeatedly recycled to leach more sludge, and there was no problem with impurity buildup.

• Research Organization: Bureau of Mines, Rolla, MO (USA). Rolla Research Center
• OSTI ID: 6497922
• Report Number(s): PB-84-199298; BM-RI-8857
• Resource Relation: Other Information: Library of Congress catalog card No. 83-600347. See also PB82-141045
• Country of Publication: United States
• Language: English

Related Subjects

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
ELECTRIC BATTERIES
RECYCLING
LEAD
MATERIALS RECOVERY
ELECTROREFINING
ELECTROCHEMICAL CELLS
ELECTROLYSIS
ELEMENTS
LYSIS
MANAGEMENT
METALS
PROCESSING
RECOVERY
REFINING
WASTE MANAGEMENT
WASTE PROCESSING
320305* - Energy Conservation
Consumption
& Utilization- Industrial & Agricultural Processes- Industrial Waste Management