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Title: In situ secondary ion mass spectrometry analysis

The direct detection of tributyl phosphate (TBP) on rocks using molecular beam surface analysis [MBSA or in situ secondary ion mass spectrometry (SIMS)] is demonstrated. Quantities as low as 250 ng were detected on basalt and sandstone with little or no sample preparation. Detection of TBP on soil has proven to be more problematic and requires further study. Ethylenediaminetetraacetic acid (EDTA) is more difficult to detect because it is very reactive with surfaces of interest. Nevertheless, it is possible to detect EDTA if the acidity of the surface is controlled. The detection of EDTA-metal complexes is currently an open question, but evidence is presented for the detection of ions arising from a EDTA-lead complex. Carboxylic acids (i.e., citric, ascorbic, malic, succinic, malonic, and oxalic) give characteristic SIM spectra, but their detection on sample surfaces awaits evaluation.
Authors:
; ; ; ;
Publication Date:
OSTI Identifier:
6483751
Report Number(s):
EGG-WTD-10507
ON: DE93012185
DOE Contract Number:
AC07-76ID01570
Resource Type:
Technical Report
Research Org:
EG and G Idaho, Inc., Idaho Falls, ID (United States)
Sponsoring Org:
DOE; USDOE, Washington, DC (United States)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 54 ENVIRONMENTAL SCIENCES; CARBOXYLIC ACIDS; DETECTION; EDTA; TBP; ION MICROPROBE ANALYSIS; LEAD COMPLEXES; MASS SPECTROSCOPY; POLYETHYLENES; ROCKS; SITE CHARACTERIZATION; SOILS; STAINLESS STEELS; SURFACES; TEFLON; US DOE; ALLOYS; AMINO ACIDS; BUTYL PHOSPHATES; CHELATING AGENTS; CHEMICAL ANALYSIS; COMPLEXES; ESTERS; FLUORINATED ALIPHATIC HYDROCARBONS; HALOGENATED ALIPHATIC HYDROCARBONS; HIGH ALLOY STEELS; IRON ALLOYS; IRON BASE ALLOYS; MATERIALS; MICROANALYSIS; NATIONAL ORGANIZATIONS; NONDESTRUCTIVE ANALYSIS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; ORGANIC POLYMERS; PETROCHEMICALS; PETROLEUM PRODUCTS; PHOSPHORIC ACID ESTERS; PLASTICS; POLY; POLYMERS; POLYOLEFINS; POLYTETRAFLUOROETHYLENE; SPECTROSCOPY; STEELS; SYNTHETIC MATERIALS; US ORGANIZATIONS 400102* -- Chemical & Spectral Procedures; 540220 -- Environment, Terrestrial-- Chemicals Monitoring & Transport-- (1990-)