Study of the interaction of palladium bis(acetylacetonate) with boron trifluoride etherate by IR and UV spectroscopy

Journal Article · Tue Oct 01 00:00:00 EDT 1985 · Sov. J. Coordinat. Chem.; (United States)

OSTI ID:6419696

Tkach, V S; Ratovskii, G V; Dmitrieva, T V; Malakhova, N D; Shmidt, F K

It has been shown in this work that the reaction of palladium bis(acetylacetonate) with boron trifluoride etherate is accompanied by the stepwise intracoordination exchange of acetylacetonato ligands for fluorine between palladium and boron. The process can proceed in two directions, depending on the initial concentration of the palladium complex and the B:Pd atomic ratio in the reaction medium. Different coordination compounds containing boron and palladium, but differing significantly in solubility in organic solvents are, accordingly, obtained.

• Research Organization: A.A. Zhdanov Irkutsk State Univ., USSR
• OSTI ID: 6419696
• Journal Information: Sov. J. Coordinat. Chem.; (United States), Vol. 10:12; Other Information: Translated from Koordinatsionnaya Khimiya; 10: No. 12, (Dec 1984)
• Country of Publication: United States
• Language: Russian

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BORON COMPLEXES
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
PALLADIUM COMPLEXES
ACETYLACETONE
BINDING ENERGY
BORON FLUORIDES
CATALYSTS
CHEMICAL BONDS
COORDINATION VALENCES
ETHERS
INFRARED SPECTRA
PRECIPITATION
QUANTITATIVE CHEMICAL ANALYSIS
QUANTITY RATIO
SOLUBILITY
SYNTHESIS
ULTRAVIOLET SPECTRA
BORON COMPOUNDS
CHELATING AGENTS
CHEMICAL ANALYSIS
COMPLEXES
ENERGY
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
KETONES
KINETICS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
REACTION KINETICS
REAGENTS
SEPARATION PROCESSES
SPECTRA
TRANSITION ELEMENT COMPLEXES
VALENCE
400201* - Chemical & Physicochemical Properties