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Title: Equilibrium CH acidity of Ni(II) complexes of Schiff's bases of amino acids with S-2-N-(N'-benzylprolyl)amino-benzaldehyde and S-2-N-(N'-benzylprolyl)aminobenzophenone

Abstract

By metal exchange in DMSO (K/sup +/ cation) pK values have been measured for a series of acids which are Ni(II) complexes of Schiff's bases of the amino acids Gly, S-Ala, and S-Val, with S-2-N-(N'-benzylprolyl)aminobenzaldehyde and S-2-N-(N'-benzylprolyl)aminobenzophenone. The amino acid fragment in the studied Ni(II) complexes possesses high acidity close to fluorene but five orders of magnitude greater than for acetophenone and approaching nitroalkanes in acidity.

Authors:
; ; ; ; ; ;
Publication Date:
Research Org.:
A.N. Nesmeyanov Institute of Heteroorganic Compounds, Moscow, USSR
OSTI Identifier:
6417035
Resource Type:
Journal Article
Journal Name:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
Additional Journal Information:
Journal Volume: 35:4; Other Information: Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya; 35: No.4, 905-909(Apr 1986)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AMINO ACIDS; EQUILIBRIUM; PH VALUE; NICKEL COMPLEXES; CATALYTIC EFFECTS; COMPLEXOMETRY; BENZALDEHYDE; BENZOPHENONE; CARBANIONS; CHEMICAL REACTION YIELD; COMPARATIVE EVALUATIONS; DMSO; ELECTRON SPIN RESONANCE; POTASSIUM COMPLEXES; SCHIFF BASES; SPECTRAL SHIFT; SPECTROPHOTOMETRY; SYNTHESIS; ULTRAVIOLET SPECTRA; ALDEHYDES; ALKALI METAL COMPLEXES; ANIONS; CARBOXYLIC ACIDS; CHARGED PARTICLES; COMPLEXES; IMINES; IONS; KETONES; MAGNETIC RESONANCE; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; RESONANCE; SPECTRA; SULFOXIDES; TRANSITION ELEMENT COMPLEXES; YIELDS; 400201* - Chemical & Physicochemical Properties

Citation Formats

Terekhova, M I, Belokon', Yu N, Maleev, V I, Chernoglazova, N I, Kochetkov, K A, Belikov, V M, and Petrov, E S. Equilibrium CH acidity of Ni(II) complexes of Schiff's bases of amino acids with S-2-N-(N'-benzylprolyl)amino-benzaldehyde and S-2-N-(N'-benzylprolyl)aminobenzophenone. United States: N. p., 1986. Web. doi:10.1007/BF00954238.
Terekhova, M I, Belokon', Yu N, Maleev, V I, Chernoglazova, N I, Kochetkov, K A, Belikov, V M, & Petrov, E S. Equilibrium CH acidity of Ni(II) complexes of Schiff's bases of amino acids with S-2-N-(N'-benzylprolyl)amino-benzaldehyde and S-2-N-(N'-benzylprolyl)aminobenzophenone. United States. https://doi.org/10.1007/BF00954238
Terekhova, M I, Belokon', Yu N, Maleev, V I, Chernoglazova, N I, Kochetkov, K A, Belikov, V M, and Petrov, E S. 1986. "Equilibrium CH acidity of Ni(II) complexes of Schiff's bases of amino acids with S-2-N-(N'-benzylprolyl)amino-benzaldehyde and S-2-N-(N'-benzylprolyl)aminobenzophenone". United States. https://doi.org/10.1007/BF00954238.
@article{osti_6417035,
title = {Equilibrium CH acidity of Ni(II) complexes of Schiff's bases of amino acids with S-2-N-(N'-benzylprolyl)amino-benzaldehyde and S-2-N-(N'-benzylprolyl)aminobenzophenone},
author = {Terekhova, M I and Belokon', Yu N and Maleev, V I and Chernoglazova, N I and Kochetkov, K A and Belikov, V M and Petrov, E S},
abstractNote = {By metal exchange in DMSO (K/sup +/ cation) pK values have been measured for a series of acids which are Ni(II) complexes of Schiff's bases of the amino acids Gly, S-Ala, and S-Val, with S-2-N-(N'-benzylprolyl)aminobenzaldehyde and S-2-N-(N'-benzylprolyl)aminobenzophenone. The amino acid fragment in the studied Ni(II) complexes possesses high acidity close to fluorene but five orders of magnitude greater than for acetophenone and approaching nitroalkanes in acidity.},
doi = {10.1007/BF00954238},
url = {https://www.osti.gov/biblio/6417035}, journal = {Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)},
number = ,
volume = 35:4,
place = {United States},
year = {Mon Oct 20 00:00:00 EDT 1986},
month = {Mon Oct 20 00:00:00 EDT 1986}
}