Iron/zeolite catalysts for synthesis of hydrocarbons from CO and H/sub 2/

Journal Article · Thu Jul 10 00:00:00 EDT 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00952836· OSTI ID:6416727

Lapidus, A L; Savel'ev, M M; Muranova, L M; Borisovich, I G; Vasserberg, V E; Minachev, Kh M

Catalysts obtained by deposition of Fe(CO)/sub 5/ on Y zeolites containing bivalent cations are active in the synthesis of C/sub 1/-C/sub 4/ hydrocarbons from CO and H/sub 2/ at 300-400/sup 0/C and atmospheric pressure. The activity of the iron-containing catalysts increases in the same order as the increase in basicity of the cation: BeY < MgY < CaY < SrY < BaY. The content of C/sub 2/-C/sub 3/ olefins in the products from synthesis at 350-373/sup 0/C on the iron-containing zeolites increases in the series BeY < MgY < CaY < SrY < BaY.

• Research Organization: N.D. Zelinskii Institute of Organic Chemistry, Moscow, USSR
• OSTI ID: 6416727
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Vol. 35:1; Other Information: Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya; 35: No.1, 23-26(Jan 1986)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON MONOXIDE
HETEROGENEOUS CATALYSIS
CARBONYLS
CATALYTIC EFFECTS
HYDROGEN
IRON COMPOUNDS
ZEOLITES
BARIUM COMPOUNDS
BERYLLIUM COMPOUNDS
CALCIUM COMPOUNDS
CATALYSTS
CHEMICAL REACTION YIELD
CHROMATOGRAPHY
COMPARATIVE EVALUATIONS
CYCLOALKANES
ETHANE
ETHYLENE
MAGNESIUM COMPOUNDS
METHANE
PROPANE
STRONTIUM COMPOUNDS
TEMPERATURE DEPENDENCE
VALENCE
ALKALINE EARTH METAL COMPOUNDS
ALKANES
ALKENES
CARBON COMPOUNDS
CARBON OXIDES
CATALYSIS
CHALCOGENIDES
ELEMENTS
HYDROCARBONS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
MATERIALS
MINERALS
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SEPARATION PROCESSES
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* - Chemical &amp; Physicochemical Properties