Cross coupling of magnesium diacetylenides with functional allylic and halide-containing compounds catalyzed by transition metal complexes

Journal Article · Wed Aug 20 00:00:00 EDT 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00952934· OSTI ID:6357377

Dzhemilev, U M; Ibragimov, A G; Saraev, R A

An efficient method has been developed for the synthesis of 1,4-enynes, conjugated acetylenes and aryl acetylenes by the cross coupling of magnesium diacetylenides with allyl ethers and esters, alkyl halides, allyl halides, aryl halides, allyl sulfides, and allylsulfones, using Ni and Pd complexes as the catalyst.

• Research Organization: Institute of Chemistry, Ufa, USSR
• OSTI ID: 6357377
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Vol. 35:2; Other Information: Translated from Izvestiya Akademii Nauk SSSR Seriya Khimicheskaya, 35: No. 4, 429-433(Feb 1986)
• Country of Publication: United States
• Language: Russian

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKYNES
CROSS-LINKING
SYNTHESIS
MAGNESIUM COMPLEXES
NICKEL COMPLEXES
CATALYTIC EFFECTS
PALLADIUM COMPLEXES
CARBON 13
CHROMATOGRAPHY
COPPER CHLORIDES
COPPER IODIDES
ELECTRON SPIN RESONANCE
ESTERS
ETHERS
INFRARED SPECTRA
IODINE
IODINE COMPLEXES
LITHIUM CHLORIDES
MASS SPECTRA
NMR SPECTRA
PALLADIUM CHLORIDES
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPLEXES
CARBON ISOTOPES
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COPPER COMPOUNDS
COPPER HALIDES
ELEMENTS
EVEN-ODD NUCLEI
HALIDES
HALOGEN COMPOUNDS
HALOGENS
HYDROCARBONS
IODIDES
IODINE COMPOUNDS
ISOTOPES
LIGHT NUCLEI
LITHIUM COMPOUNDS
LITHIUM HALIDES
MAGNETIC RESONANCE
NONMETALS
NUCLEI
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PALLADIUM COMPOUNDS
POLYMERIZATION
RESONANCE
SEPARATION PROCESSES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties