Crystal structure of dichlorobis(2-amino-5-methyl-1,3,4-thiadiazole)dicopper(I)
An x-ray diffraction investigation of dichlorobis(2-amino-5-methyl-1,3,4-thiadiazole)dicopper(I) has been carried out. The crystals are monoclinic: a = 6.365(2), b = 9.353(3), c = 11.456(3) A, el = 100.51(3), space group P21/b, Z = 2. The intensities of 1620 reflections with I > 3sigma were measured on a Syntex P21 diffractometer (Mo K radiation). The structure was refined by the least-squares method to R = 0.055. The hydrogen atoms have been located. The molecule of the complex is a flat centrosymmetric dimer, in which the N atoms of the hydrazine residues are bridging atoms and join two Cu atoms to form a six-membered metallocycle. The environment of each Cu atom is a trigonal pyramid. In its base there are two atoms and a Cl atom, and at its apex there is a Cl atom from an adjacent complex. The Cu-N distances are equal to 1.194 and 2.025, the Cu-Cl distance is equal to 2.333, and the Cu-Cl/sub apic/ distance is equal to 2.699 A. The interatomic distances in the ligand are consistent with the literature data. The five-membered heterocycles deviate 10 from the plane of the metallocycle.
- Research Organization:
- N.P. Ogarev, Mordovian State Univ., USSR
- OSTI ID:
- 6294700
- Journal Information:
- Sov. J. Coordinat. Chem.; (United States), Vol. 12:6; Other Information: Translated from Koordinatsionnaya Khimiya; 12: No.6, 830-834(Jun 1986)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
COPPER COMPLEXES
CATALYTIC EFFECTS
MONOCLINIC LATTICES
X-RAY DIFFRACTION
THIADIAZOLES
BINDING ENERGY
BOND ANGLE
BOND LENGTHS
CATALYSTS
CHEMICAL BONDS
COMPUTERIZED SIMULATION
COORDINATION VALENCES
INTERATOMIC DISTANCES
K CODES
LATTICE PARAMETERS
LEAST SQUARE FIT
LIGANDS
MOLECULAR STRUCTURE
ORGANIC CHLORINE COMPOUNDS
SPACE GROUPS
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
AZOLES
COHERENT SCATTERING
COMPLEXES
COMPUTER CODES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DIFFRACTION
DIMENSIONS
DISTANCE
ENERGY
HETEROCYCLIC COMPOUNDS
LENGTH
MAXIMUM-LIKELIHOOD FIT
NUMERICAL SOLUTION
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
SCATTERING
SIMULATION
TRANSITION ELEMENT COMPLEXES
VALENCE
400201* - Chemical & Physicochemical Properties
360602 - Other Materials- Structure & Phase Studies