Permeation of gas mixtures in cellulose acetate membranes - practical approach to predict the permeation rate CO/sub 2//CH/sub 4/ mixture
Dry cellulose acetate reverse osmosis membranes of different porosities are prepared by using the solvent exchange method and then shrunk at various temperatures. Permeation of single gases and gas mixtures of CO/sub 2/ and CH/sub 4/ through these membranes were investigated at various upstream pressures up to 2.4 MPa. The permeation data of a reference gas usually helium was used to characterize the membrane and determine the flow parameters which can be used to predict the performance of that membrane in separating gas mixtures. The Surface Force - Pore Flow model developed in previous investigations can be used to predict the membrane performance using the above method. The prediction using the characterization parameters of the reference gas proved to be unsatisfactory in most cases, since the surface force is highly dependent on the interaction between the specific gas component in the mixture and the membrane.
- Research Organization:
- National Research Council of Canada, Ottawa
- OSTI ID:
- 6256103
- Report Number(s):
- CONF-871038-
- Journal Information:
- Sep. Sci. Technol.; (United States), Vol. 23:12,13; Conference: 5. symposium on separation science and technology for energy applications, Knoxville, TN, USA, 26 Oct 1987
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ACETATES
PERMEABILITY
CARBON DIOXIDE
OSMOSIS
CELLULOSE
MEMBRANES
PERFORMANCE
METHANE
EXPERIMENTAL DATA
GASES
MATHEMATICAL MODELS
MEDIUM PRESSURE
MIXTURES
POROSITY
PREDICTION EQUATIONS
ALKANES
CARBOHYDRATES
CARBON COMPOUNDS
CARBON OXIDES
CARBOXYLIC ACID SALTS
CHALCOGENIDES
DATA
DIFFUSION
DISPERSIONS
EQUATIONS
FLUIDS
HYDROCARBONS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
POLYSACCHARIDES
SACCHARIDES
400105* - Separation Procedures