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Title: Permeation of gas mixtures in cellulose acetate membranes - practical approach to predict the permeation rate CO/sub 2//CH/sub 4/ mixture

Conference · · Sep. Sci. Technol.; (United States)
OSTI ID:6256103

Dry cellulose acetate reverse osmosis membranes of different porosities are prepared by using the solvent exchange method and then shrunk at various temperatures. Permeation of single gases and gas mixtures of CO/sub 2/ and CH/sub 4/ through these membranes were investigated at various upstream pressures up to 2.4 MPa. The permeation data of a reference gas usually helium was used to characterize the membrane and determine the flow parameters which can be used to predict the performance of that membrane in separating gas mixtures. The Surface Force - Pore Flow model developed in previous investigations can be used to predict the membrane performance using the above method. The prediction using the characterization parameters of the reference gas proved to be unsatisfactory in most cases, since the surface force is highly dependent on the interaction between the specific gas component in the mixture and the membrane.

Research Organization:
National Research Council of Canada, Ottawa
OSTI ID:
6256103
Report Number(s):
CONF-871038-
Journal Information:
Sep. Sci. Technol.; (United States), Vol. 23:12,13; Conference: 5. symposium on separation science and technology for energy applications, Knoxville, TN, USA, 26 Oct 1987
Country of Publication:
United States
Language:
English