Skeletal isomerization accompanying the reactions of the thiabirdcage hydroxy derivative. Synthesis of sulfur-containing oxabirdcage derivatives

Journal Article · Sat Sep 20 00:00:00 EDT 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6137004

Tolstikov, G A; Lerman, B M; Belogaeva, T A; Sultanova, V S; Khalilov, L M; Panasenko, A A

The thermolysis and oxidation of the hydroxy derivative of the diabirdcage compound in acetic acid is accompanied by skeletal isomerization and leads to mono- and biframework sulfur-containing derivatives of oxabirdcage. It was established by the /sup 13/C NMR method that the biframework compounds with S, SS, and SO/sub 2/ bridges are formed as mixtures of the erythro and threo isomers.

• Research Organization: Institute of Chemistry, Ufa, USSR
• OSTI ID: 6137004
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 22:4; Other Information: Translated from Zh. Org. Khim.; 22: No. 4, 781-785(Apr 1986)
• Country of Publication: United States
• Language: Russian

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
CYCLOALKANES
ISOMERIZATION
MOLECULAR STRUCTURE
NMR SPECTRA
HYDROXY COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ACETIC ACID
CARBON 13
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL SHIFT
CHLOROFORM
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
DISULFIDES
DODECANE
HYDROGEN 1
HYPERFINE STRUCTURE
INFRARED SPECTRA
ISOMERS
J-J COUPLING
KETONES
MASS SPECTRA
MULTIPLETS
NICKEL
OXIDATION
PYROLYSIS
PYROLYSIS PRODUCTS
SULFONES
SYNTHESIS
THIOLS
ALKANES
CARBON ISOTOPES
CARBOXYLIC ACIDS
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
COUPLING
DECOMPOSITION
ELEMENTS
EVEN-ODD NUCLEI
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
INTERMEDIATE COUPLING
ISOTOPES
LIGHT NUCLEI
METALS
MONOCARBOXYLIC ACIDS
NUCLEI
ODD-EVEN NUCLEI
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
SPECTRA
STABLE ISOTOPES
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENTS
400201* - Chemical & Physicochemical Properties
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory