Kinetics and mechanism of the liquid-phase oxidation of cyclohexene. V. Oxidation of cyclohexene in the presence of bimetallic catalysts

Journal Article · Tue Nov 01 00:00:00 EST 1988 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:6093727

Baevskii, M Yu; Litvintsev, I Yu; Sapunov, V N

The kinetics of the liquid-phase oxidation of cyclohexene in the presence of homogeneous bimetallic catalysts Co-V, Pb-V, Pb-Mo was investigated. It was shown that the activity of the bimetallic catalyst found is determined to a large degree by the nature of the epoxiding metal. A general model is proposed for the oxidation of cyclohexene in the presence of bimetallic catalysts.

• Research Organization: D.I. Mendeleev Chemico-technological Institute, Moscow (USSR)
• OSTI ID: 6093727
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 29:3; Other Information: Translated from Kinet. Katal.; 29: No. 3, 575-580(May-Jun 1988)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
COBALT COMPOUNDS
CATALYTIC EFFECTS
CYCLOALKENES
OXIDATION
MOLYBDENUM COMPOUNDS
VANADIUM COMPOUNDS
BIMETALS
CATALYSTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
DECOMPOSITION
EPOXIDES
HETEROGENEOUS CATALYSIS
MATHEMATICAL MODELS
PEROXIDES
REDOX POTENTIAL
ALKENES
CATALYSIS
CHEMICAL REACTIONS
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXYGEN COMPOUNDS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* - Chemical & Physicochemical Properties