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Title: New dual-phase polymer electrolytes prepared from NBR/SBR lattices. [polyacryloNitrile-Butadiene Rubber/poly(Styrene-Butadiene) copolymer Rubber]

Abstract

A new type of Li[sup +] ion conducting polymer electrolytes consisting of two phases, one of which is a highly polar region (impregnated with lithium salt solution), forming ion-conductive channels, while the other is a nonpolar region, forming supporting polymer matrices have been prepared from NBR/SBR lattices. TEM measurement and EDX analysis show evidence that dual-phase structure is constructed in the electrolyte. Ionic conductivity of the electrolyte increases with increase of lithium salt solution content. Maximum ionic conductivity of 2.2 [times] 10[sup [minus]3] S/cm is obtained at the lithium salt solution content of 60.5% (w/w). The electrolyte retains rubber-like film with good mechanical strength despite the presence of the solution.

Authors:
; ; ;  [1]
  1. Nippon Telegraph and Telephone Corp., Tokyo (Japan). NTT Interdisciplinary Research Lab.
Publication Date:
OSTI Identifier:
6018950
Resource Type:
Journal Article
Journal Name:
Journal of the Electrochemical Society; (United States)
Additional Journal Information:
Journal Volume: 140:10; Journal ID: ISSN 0013-4651
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; SOLID ELECTROLYTES; FABRICATION; IONIC CONDUCTIVITY; LATEX; LITHIUM COMPOUNDS; MECHANICAL PROPERTIES; PHASE STUDIES; POLYMERS; ALKALI METAL COMPOUNDS; ELASTOMERS; ELECTRIC CONDUCTIVITY; ELECTRICAL PROPERTIES; ELECTROLYTES; ORGANIC COMPOUNDS; ORGANIC POLYMERS; PHYSICAL PROPERTIES; RUBBERS; 250903* - Energy Storage- Batteries- Materials, Components, & Auxiliaries

Citation Formats

Matsumoto, Morihiko, Ichino, Toshihiro, Rutt, J S, and Nishi, Shiro. New dual-phase polymer electrolytes prepared from NBR/SBR lattices. [polyacryloNitrile-Butadiene Rubber/poly(Styrene-Butadiene) copolymer Rubber]. United States: N. p., 1993. Web. doi:10.1149/1.2220957.
Matsumoto, Morihiko, Ichino, Toshihiro, Rutt, J S, & Nishi, Shiro. New dual-phase polymer electrolytes prepared from NBR/SBR lattices. [polyacryloNitrile-Butadiene Rubber/poly(Styrene-Butadiene) copolymer Rubber]. United States. https://doi.org/10.1149/1.2220957
Matsumoto, Morihiko, Ichino, Toshihiro, Rutt, J S, and Nishi, Shiro. 1993. "New dual-phase polymer electrolytes prepared from NBR/SBR lattices. [polyacryloNitrile-Butadiene Rubber/poly(Styrene-Butadiene) copolymer Rubber]". United States. https://doi.org/10.1149/1.2220957.
@article{osti_6018950,
title = {New dual-phase polymer electrolytes prepared from NBR/SBR lattices. [polyacryloNitrile-Butadiene Rubber/poly(Styrene-Butadiene) copolymer Rubber]},
author = {Matsumoto, Morihiko and Ichino, Toshihiro and Rutt, J S and Nishi, Shiro},
abstractNote = {A new type of Li[sup +] ion conducting polymer electrolytes consisting of two phases, one of which is a highly polar region (impregnated with lithium salt solution), forming ion-conductive channels, while the other is a nonpolar region, forming supporting polymer matrices have been prepared from NBR/SBR lattices. TEM measurement and EDX analysis show evidence that dual-phase structure is constructed in the electrolyte. Ionic conductivity of the electrolyte increases with increase of lithium salt solution content. Maximum ionic conductivity of 2.2 [times] 10[sup [minus]3] S/cm is obtained at the lithium salt solution content of 60.5% (w/w). The electrolyte retains rubber-like film with good mechanical strength despite the presence of the solution.},
doi = {10.1149/1.2220957},
url = {https://www.osti.gov/biblio/6018950}, journal = {Journal of the Electrochemical Society; (United States)},
issn = {0013-4651},
number = ,
volume = 140:10,
place = {United States},
year = {Fri Oct 01 00:00:00 EDT 1993},
month = {Fri Oct 01 00:00:00 EDT 1993}
}