Kinetic resolution of acids in acylation reactions in the presence of chiral tertiary amines
Journal Article
·
· J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6008138
Asymmetric synthesis has now become an important method for the production of optically active compounds, and its most attractive form is asymmetric catalysis. This work was devoted to an investigation into asymmetric catalysis with chiral tertiary amines in acylation reactions. During the acylation of alcohols and amines by the action of racemic 2-phenylpropionic and 2-methyl-3-phenylpropionic acids in the presence of S-nicotine the initial acids are resolved kinetically. The (R)-2-phenylpropionic acid obtained in this way had an optical purity of 0.5-1.5%.
- Research Organization:
- M.V. Lomonosov Moscow State Univ. (USSR)
- OSTI ID:
- 6008138
- Journal Information:
- J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 24:2; Other Information: Translated from Zh. Org. Khim.; 24: No. 2, 343-348 (Feb 1988)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALCOHOLS
ACYLATION
AMINES
NICOTINE
CATALYTIC EFFECTS
ASYMMETRY
CHEMICAL REACTION KINETICS
ETHANOL
IMIDES
INFRARED SPECTRA
METHANOL
NMR SPECTRA
OPTICAL PROPERTIES
PHENOL
PROPIONIC ACID
RESOLUTION
STEREOCHEMISTRY
ALKALOIDS
AROMATICS
AUTONOMIC NERVOUS SYSTEM AGENTS
AZINES
AZOLES
CARBOXYLIC ACIDS
CHEMICAL REACTIONS
DRUGS
HETEROCYCLIC COMPOUNDS
HYDROXY COMPOUNDS
KINETICS
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PARASYMPATHOLYTICS
PARASYMPATHOMIMETICS
PHENOLS
PHYSICAL PROPERTIES
PYRIDINES
PYRROLES
PYRROLIDINES
REACTION KINETICS
SPECTRA
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALCOHOLS
ACYLATION
AMINES
NICOTINE
CATALYTIC EFFECTS
ASYMMETRY
CHEMICAL REACTION KINETICS
ETHANOL
IMIDES
INFRARED SPECTRA
METHANOL
NMR SPECTRA
OPTICAL PROPERTIES
PHENOL
PROPIONIC ACID
RESOLUTION
STEREOCHEMISTRY
ALKALOIDS
AROMATICS
AUTONOMIC NERVOUS SYSTEM AGENTS
AZINES
AZOLES
CARBOXYLIC ACIDS
CHEMICAL REACTIONS
DRUGS
HETEROCYCLIC COMPOUNDS
HYDROXY COMPOUNDS
KINETICS
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PARASYMPATHOLYTICS
PARASYMPATHOMIMETICS
PHENOLS
PHYSICAL PROPERTIES
PYRIDINES
PYRROLES
PYRROLIDINES
REACTION KINETICS
SPECTRA
400201* - Chemical & Physicochemical Properties