Actinide thermodynamic predictions. 3. Thermodynamics of compounds and aquo ions of the 2+, 3+ and 4+ oxidation states and standard electrode potentials at 298. 15 K

Journal Article · Thu Jan 16 00:00:00 EST 1986 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100274a021· OSTI ID:5952319

Bratsch, S G; Lagowski, J J

A modified ionic model is applied to selected actinide thermodynamic measurements to allow the evaluation of gas-phase ion thermodynamics across the actinide series. These are used to predict the thermodynamic properties of a number of actinide compounds and aquo ions at 298.15 K. General guidelines are offered for predicting the relative stabilities of actinide(II), -(III), and -(IV) compounds in various chemical environments. 40 references, 6 figures, 8 tables.

• Research Organization: Univ. of Texas, Austin
• OSTI ID: 5952319
• Journal Information: J. Phys. Chem.; (United States), Vol. 90:2
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
ACTINIUM COMPOUNDS
ELECTRODES
THERMODYNAMIC PROPERTIES
VALENCE
AMERICIUM COMPOUNDS
BERKELIUM COMPOUNDS
CALIFORNIUM COMPOUNDS
CATIONS
CURIUM COMPOUNDS
EINSTEINIUM COMPOUNDS
ELEMENT 104 COMPOUNDS
FERMIUM COMPOUNDS
LAWRENCIUM COMPOUNDS
MENDELEVIUM COMPOUNDS
NEPTUNIUM COMPOUNDS
NOBELIUM COMPOUNDS
RADIUM COMPOUNDS
THORIUM COMPOUNDS
URANIUM COMPOUNDS
AQUEOUS SOLUTIONS
EXPERIMENTAL DATA
GASES
ACTINIDE COMPOUNDS
ALKALINE EARTH METAL COMPOUNDS
CHARGED PARTICLES
DATA
DISPERSIONS
FLUIDS
INFORMATION
IONS
MIXTURES
NUMERICAL DATA
PHYSICAL PROPERTIES
SOLUTIONS
TRANSPLUTONIUM COMPOUNDS
TRANSURANIUM COMPOUNDS
400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials