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Title: Physical properties of kraft black liquor: Summary report, Phases 1 and 2

Technical Report ·
OSTI ID:5851245

Since 1981, a research program has been in progress to determine the physical properties of kraft black liquors and to develop methods for reduction of data and correlation of properties with pumping conditions. The basic premise that has been used to direct the research program is that kraft black liquor behaves as a polymer solution, particularly at high solids, and that the behavior is dominated by the characteristics of the lignin present. This premise is proving to be correct, and the principles that follow from this premise are proving to be successful for data reduction and correlation. The research has been a complex program involving experimental pulping, chemical analysis, lignin separation and characterization, thermal analysis, rheological measurements, and considerable equipment and methods development. Due to the complexity of the program, the unforeseen need to expend a great deal of effort in development of experimental techniques for analysis, and the fact that our liquors proved to be unstable at high temperatures and solids, all of the original objectives could not be accomplished. However, our program has added substantially to the body of knowledge of physical properties of black liquor. Our results indicate that the goal of developing correlations for physical properties of kraft black liquor is practical and can be realized through extension of the present work.

Research Organization:
Florida Univ., Gainesville (USA); Maine Univ., Orono (USA)
DOE Contract Number:
AC02-82CE40606; FG02-85CE40740
OSTI ID:
5851245
Report Number(s):
DOE/CE/40606-T5; ON: DE88002991
Resource Relation:
Other Information: Portions of this document are illegible in microfiche products. Original copy available until stock is exhausted
Country of Publication:
United States
Language:
English