Intercalation reactions of the neptunyl(vi) dication with hydrogen uranyl phosphate and hydrogen neptunyl phosphate host lattices. Technical report

Technical Report · Wed May 17 00:00:00 EDT 1989

OSTI ID:5845660

Dorhout, P K; Kissane, R J; Abney, K D; Avens, L R; Eller, G

The hydrated layered solids, hydrogen uranyl phosphate. HUO/sub 2/PO/sub 4/, HUP, and its isostructural neptunyl analog, HNpO/sub 2/PO/sub 4/, HNPP, can be intercalated with UO/sub 2/(2+) and NPO/sub 2/(2+) ions to yield a family of layered, hydrated solids that have been characterized by X-ray powder diffraction and by infrared, Raman, and electronic spectroscopy. Aqueous reactions of HUP with UO/sub 2/(2+) and of HNPP with NPO/sub 2/(2+) lead to hydrated layered solids, (UO/sub 2/)3(PO/sub 4/)/sub 2/, UP, and (NPO/sub 2/)/sub 3/(PO/sub 4/)/sub 2/, NPP; preparation of UP from HUP and of NPP from HNPP can also be effected by thermal decomposition of the parent solids, thus affording a set of self intercalation reactions that are reversible. Cross-intercalation reactions (UO/sub 2/(2+) into HNPP; NPO/sub 2/(2+) into HUP) also proceed under stoichiometric conditions.

• Research Organization: Wisconsin Univ., Madison, WI (USA). Dept. of Chemistry
• OSTI ID: 5845660
• Report Number(s): AD-A-208216/2/XAB; UWIS/DC/TR-89/5
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CLATHRATES
CHEMICAL REACTIONS
NEPTUNYL COMPOUNDS
URANYL COMPOUNDS
CHELATES
HYDRATES
HYDROGEN
LAYERS
LIQUIDS
PHOSPHATES
POWDERS
PROGRESS REPORT
PYROLYSIS
SOLIDS
SPECTROSCOPY
STOICHIOMETRY
URANIUM COMPOUNDS
X-RAY DIFFRACTION
ACTINIDE COMPOUNDS
COHERENT SCATTERING
COMPLEXES
DECOMPOSITION
DIFFRACTION
DOCUMENT TYPES
ELEMENTS
FLUIDS
NEPTUNIUM COMPOUNDS
NONMETALS
OXYGEN COMPOUNDS
PHOSPHORUS COMPOUNDS
SCATTERING
THERMOCHEMICAL PROCESSES
TRANSURANIUM COMPOUNDS
400102* - Chemical & Spectral Procedures