Modular self-assembly, characterization, and host-guest chemistry of nanoscale organometallic architectures

Conference · Wed Dec 31 00:00:00 EST 1997

OSTI ID:560179

Manna, J; Kuehl, C J; Stang, P J ^[1]; Muddiman, D C; Smith, R D ^[2]

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1. Univ. of Utah, Salt Lake City, UT (United States)
2. Pacific Northwest National Lab., Richland, WA (United States)

The supramolecular synthesis and chemistry of organic macrocycles has been the focus of considerable study for over thirty years. In contrast, the chemistry of analogous inorganic and organometallic macrocycles is in it infancy; little is know about the stability, spectroscopic and physical properties, and chemistry of these species. We will report on the design of several unique supramolecular macrocycles and the characterization of these species by a range of spectroscopic techniques, including electrospray-ionization Fourier transform ion cyclotron resonance spectrometry. Preliminary data concerning the host-guest chemistry of these macrocycles will also be presented.

• OSTI ID: 560179
• Report Number(s): CONF-970443-; TRN: 97:005895-0180
• Resource Relation: Conference: 213. national meeting of the American Chemical Society, San Francisco, CA (United States), 13-17 Apr 1997; Other Information: PBD: 1997; Related Information: Is Part Of 213th ACS national meeting; PB: 2904 p.
• Country of Publication: United States
• Language: English

Related Subjects

40 CHEMISTRY
ORGANOMETALLIC COMPOUNDS
ION CYCLOTRON-RESONANCE
IONIZATION
PHYSICAL PROPERTIES
STABILITY