Reactions of carbon dioxide with bis(trimethylsilyl)amino derivatives of lanthanides

Journal Article · Sun Aug 10 00:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5353374

Rad'kov, Yu F; Fedorova, E A; Khorshev, S Ya; Kalinina, G S; Bochkarev, M N; Razuvaev, G A

The aminolanthanides ((Me/sub 3/Si)/sub 2/N)/sub x/Ln (Ln = Pr, Nd, Sm, Eu, Yb; x = 2, 3) under normal conditions take up 2 or 3 moles of carbon dioxide. The reactions are accompanied by secondary processes, leading to the formation of Me/sub 3/SiNCO, (Me/sub 3/Si)/sub 2/O, Me/sub 3/SiNCNSiMe/sub 3/, and an unidentified substance containing coordinated CO/sub 2/. A general scheme is proposed for the process

• Research Organization: Institute of Chemistry, Gor'kii (USSR)
• OSTI ID: 5353374
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Vol. 56:2; Other Information: Translated from Zh. Obshch. Khim.; 56: No. 2, 386-389(Feb 1986)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON DIOXIDE
COMPLEXOMETRY
RARE EARTH COMPLEXES
INFRARED SPECTRA
ISOMERIZATION
ACTIVATION ENERGY
AMINES
CARBAMATES
CARBONATES
EUROPIUM COMPLEXES
NEODYMIUM COMPLEXES
PRASEODYMIUM COMPLEXES
QUANTITY RATIO
SAMARIUM COMPLEXES
SILICON COMPLEXES
SILOXANES
YTTERBIUM COMPLEXES
CARBON COMPOUNDS
CARBON OXIDES
CARBONIC ACID DERIVATIVES
CARBOXYLIC ACID SALTS
CHALCOGENIDES
CHEMICAL REACTIONS
COMPLEXES
ENERGY
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SILICON COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SPECTRA
400201* - Chemical & Physicochemical Properties