Polarized absorption spectra of aromatic radicals in stretched polymer film. 3. Radical ions of acridine and phenazine

Journal Article · Thu Feb 21 00:00:00 EST 1980 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100441a023· OSTI ID:5343358

Sekigucki, K; Hiratsuka, H; Tanizaki, Y; Hatano, Y

Radical anions and cations of acridine and phenazine have been prepared in polymer film by ..gamma..-ray irradiation at 77 K. For the preparation of radical anions the sample was incorporated into polyethylene film by sec-butylamine, while for radical cations poly(vinyl chloride) film and sec-butyl chloride were used. Polarized absorption spectra of these radical ions have been measured in stretched polymer film and analyzed qualitatively in terms of molecular orbital calculations.

• Research Organization: Tokyo Inst. of Technology, Japan
• OSTI ID: 5343358
• Journal Information: J. Phys. Chem.; (United States), Vol. 84:4
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
ACRIDINES
CHEMICAL RADIATION EFFECTS
PHENAZINE
ABSORPTION SPECTRA
EXPERIMENTAL DATA
FILMS
GAMMA RADIATION
ISOLATED VALUES
POLYETHYLENES
PVC
AZINES
CHEMISTRY
CHLORINATED ALIPHATIC HYDROCARBONS
DATA
DATA FORMS
ELECTROMAGNETIC RADIATION
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
INFORMATION
IONIZING RADIATIONS
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
POLYMERS
POLYOLEFINS
POLYVINYLS
PYRAZINES
PYRIDINES
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
SPECTRA
400600* - Radiation Chemistry