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Title: Penta(cyclopentadienyl)-[eta]5-cyclopentadienylmanganesetricarbonyl: Structure and laser-induced conversion to fullerenes

The title compound [Cp5CpMn(CO)3], 1, has been characterized by X-ray crystallography and shown by laser-induced desorption/ionization (LDI) to undergo coalescence to fullerene C60 and other carbon clusters.
Authors:
; ; ; ; ;
Publication Date:
OSTI Identifier:
5242951
Report Number(s):
LBNL-44851
Journal ID: ISSN 0022-368X; CODEN: JORCAI
DOE Contract Number:
AC03-76SF00098
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Organometallic Chemistry; Journal Volume: 572:1; Other Information: Submitted to Journal of Organometallic Chemistry; Volume 572: No.1, (28 Aug 1998)
Research Org:
Lawrence Berkeley National Lab., CA (United States)
Sponsoring Org:
USDOE Director, Office of Science (United States)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; MANGANESE COMPOUNDS; ORGANOMETALLIC COMPOUNDS; CRYSTAL STRUCTURE; LASER-RADIATION HEATING; DESORPTION; IONIZATION; FULLERENES; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS; ORGANIC COMPOUNDS; PLASMA HEATING; SORPTION; CARBON; HEATING; NONMETALS 360602* -- Other Materials-- Structure & Phase Studies; 360601 -- Other Materials-- Preparation & Manufacture