Quaternary system SrO-CaO-BaO-CuO at 950 C. 2: Phase equilibria related to the substitution Sr/Ba in (Sr/Ba){sub 2}Ca{sub 2}Cu{sub 2}Cu{sub 3}O{sub 7} and (Sr/Ba){sub 2}CaCu{sub 2}O{sub 5} samples
- Univ. Claude Bernard-Lyon I, Villeurbanne (France)
A partial study of the solid-solid equilibria in the quaternary system BaO-SrO-CaO-CuO has been undertaken in order to determine the observed phases and their evolution when Ba is substituted for Sr in mixtures (Sr/Ba){sub 2}CaCu{sub 2}O{sub x} and (Sr/Ba){sub 2}Ca{sub 2}Cu{sub 3}O{sub x}. The temperature was fixed at 950 C and samples were elaborated under 1 bar of flowing oxygen. It has been shown that two four-phased domains exist in this quaternary system, including the following phases: ({und Ba}/Sr/Ca)CuO{sub 2}, ({und Sr/Ca}/Ba){sub 2}CuO{sub 3}, ({und Sr/Ca}/Ba){sub 14}Cu{sub 24}O{sub x}, and Ba{sub 4}CaCu{sub 3}O{sub 8} substituted Sr/Ca for the one and ({und Ba}/Sr/Ca)CuO{sub 2}, ({und Sr/Ca}/Ba){sub 2}CuO{sub 3}, ({und Sr/Ca}/Ba){sub 14}Cu{sub 24}O{sub x}, and ({und Sr/Ca}/Ba/)CuO{sub 2} for the other.
- OSTI ID:
- 522371
- Journal Information:
- Materials Research Bulletin, Vol. 32, Issue 8; Other Information: PBD: Aug 1997
- Country of Publication:
- United States
- Language:
- English
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Quaternary system SrO-CaO-BaO-CuO at 950 C. 1: Phase relationships in the limiting ternary system SrO-CaO-CuO