Identification and stability of U sub 2 O sub 2 , U sub 2 O sub 3 , and U sub 2 O sub 4 gaseous oxides molecules
Abstract
The U{sub 2}O{sub 3}{sub ({ital g})} and U{sub 2}O{sub 4}{sub ({ital g})} species have been for the first time identified by Knudsen cell-mass spectrometry and their heats of formation and atomization energies have been tentatively derived. A redetermination of these quantities for the already known UO{sub 3}{sub ({ital g})} and U{sub 2}O{sub 2}{sub ({ital g})} molecules has been also attempted.
- Authors:
-
- Centro di Studio per la Termodinamica Chimica alle Alte Temperature, C.N.R., c/o Dipartimento di Chimica, Universita di Roma La Sapienza', P. le Aldo Moro 5, 00185 Roma (Italy)
- Dipartimento di Chimica, Universita di Roma La Sapienza', P. le Aldo Moro 5, 00185 Roma (Italy)
- Publication Date:
- OSTI Identifier:
- 5201980
- Resource Type:
- Journal Article
- Journal Name:
- Journal of Chemical Physics; (United States)
- Additional Journal Information:
- Journal Volume: 95:7; Journal ID: ISSN 0021-9606
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; URANIUM OXIDES; FORMATION HEAT; ATOMIZATION; EVAPORATION; GASES; IONIZATION POTENTIAL; MASS SPECTROSCOPY; SYNTHESIS; VERY HIGH TEMPERATURE; ACTINIDE COMPOUNDS; CHALCOGENIDES; ENTHALPY; FLUIDS; OXIDES; OXYGEN COMPOUNDS; PHASE TRANSFORMATIONS; PHYSICAL PROPERTIES; REACTION HEAT; SPECTROSCOPY; THERMODYNAMIC PROPERTIES; URANIUM COMPOUNDS; 400201* - Chemical & Physicochemical Properties
Citation Formats
Guido, M, and Balducci, G. Identification and stability of U sub 2 O sub 2 , U sub 2 O sub 3 , and U sub 2 O sub 4 gaseous oxides molecules. United States: N. p., 1991.
Web. doi:10.1063/1.461652.
Guido, M, & Balducci, G. Identification and stability of U sub 2 O sub 2 , U sub 2 O sub 3 , and U sub 2 O sub 4 gaseous oxides molecules. United States. https://doi.org/10.1063/1.461652
Guido, M, and Balducci, G. 1991.
"Identification and stability of U sub 2 O sub 2 , U sub 2 O sub 3 , and U sub 2 O sub 4 gaseous oxides molecules". United States. https://doi.org/10.1063/1.461652.
@article{osti_5201980,
title = {Identification and stability of U sub 2 O sub 2 , U sub 2 O sub 3 , and U sub 2 O sub 4 gaseous oxides molecules},
author = {Guido, M and Balducci, G},
abstractNote = {The U{sub 2}O{sub 3}{sub ({ital g})} and U{sub 2}O{sub 4}{sub ({ital g})} species have been for the first time identified by Knudsen cell-mass spectrometry and their heats of formation and atomization energies have been tentatively derived. A redetermination of these quantities for the already known UO{sub 3}{sub ({ital g})} and U{sub 2}O{sub 2}{sub ({ital g})} molecules has been also attempted.},
doi = {10.1063/1.461652},
url = {https://www.osti.gov/biblio/5201980},
journal = {Journal of Chemical Physics; (United States)},
issn = {0021-9606},
number = ,
volume = 95:7,
place = {United States},
year = {Tue Oct 01 00:00:00 EDT 1991},
month = {Tue Oct 01 00:00:00 EDT 1991}
}
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